There are today available a number of pigments. In
fact after the advent of Synthetic Pigments there has evolved various
classes of pigments that are suited to particular types of Industries.
Inorganic
Pigments- They are of the type mineral-earth but generally are
metallic oxides or synthetics. Pigments that are of the type
Mineral-earth are very simple and naturally occurring colored
substances. The preparation process is also simple and consists of the
steps of washing drying, pulverizing and mixing into a formulation. The
following table shows the refractive index of some of the very popular
class of inorganic pigments.
| Pigment |
Refractive Index |
| TiO2 (rutile) |
2.71 |
| TiO2 (Anatase) |
2.55 |
| Antimony Oxide |
2.20 |
| Zinc Oxide |
2.01 |
| Calcium Carbonate |
1.65 |
| Fumed Silica |
1.45 |
Examples of inorganic pigments can be materials like lead oxide, cobalt
blue, chromium oxide, cadmium yellow, molybdate orange, and nickel
titanate. As new environmental laws are very strict about toxicity a few
of these heavy metal pigments are no longer in use.
Organic
Pigments- Organic Pigments are not usually found in nature. That is
the reason that a majority of these pigments are chemically synthesized.
They contain carbon and comes with relatively low levels of toxicity,
not providing any major environmental concern. Raw materials can include
coal tar and petroleum distillates that are transformed into insoluble
precipitates. Traditionally organic pigments are used as mass
colourants. They are popular in plastics, synthetic fibers and as
surface coatings-paints and inks. In recent years the organic pigments
are used for hi-tech applications that includes photo-reprographics,
opto-electronic displays and optical data storage.
Categories of Organic Pigments
Organic pigments are generally categorized into six types :
- Monoazo Pigments
- Diazo Pigments
- Acid and base dye Pigments
- Phthalocyanine Pigments
- Quinacridone Pigments
- Other polycyclic Pigments
Chemical structure of an Azo Pigment
Key features and characteristics of Organic Pigments
- Very good stability to solvents, light, heat, and weathering
- Good tinctorial strength
- Cost effectiveness
- Consistency and unique shades
- Completely non-toxic
- Very bright, pure, rich colors
- Organic pigments shows good color strength
As these days Metallic Pigments are a very popular
category of Pigments, a further classification can be done for the
metallic pigments.
Metallic pigments, can be of two types aluminum and zinc.
Aluminium
Pigments: Aluminium pigments are further divided into two categories
namely leafing grade and non-leafing grade. The aluminum pigments are
produced from aluminium that has purity in the range of 99.3-99.97%. The
particle has lamellar shape with 0.1-2 um in thickness and diameter of
0.5-200 um. These pigments founds use in automotive topcoats.
Some of the preferred applications of Aluminium Pigments are the
following:
- As Corrosion protection coats
- As Reflective paints
- In Marine paints (covering coats)
- Roof coatings
- In Heat-proof and highly heat-resistance paints
- Chrome effect paints
- Aerosols
Zinc
Pigments: Zinc Pigments come in two forms of powder and dust.
Usually the zinc dust is finer as compared to powder and is spherical in
shape. The dust also has a light coating of zinc oxide.
The following table cites some popular Zinc Pigments along with their
applications.
| Zinc Pigments |
Application |
| Zinc dust |
Chemical applications Metallurgical applications |
| Zinc phosphate |
Active ingredient in domestic cleaning products |
| Zinc oxide |
Agricultural applications
Rubber industry
Brick kilns
Ceramics |
The commercial performance of organic pigments are
guided by the following capabilities:
- Coloristic performance
- Rheological behaviour
- Durability
- Ecological compatibility
- Tinctorial strength
- Opacity
- Resistance to heat