(a) Molecular ion peak is the peak with the highest m/e value, usually correpond to the Mr of the molecule.

The diagram shows the mass spectrum of an alkane, X. What is X likely to be?

A C10H22
B C6H14
C C5H12
D C3H8


m/e value of molecular ion peak = 72
Therefore the Mr of X is 72.

Choice A:
Mr of C10H22 = 10 x 12.0 + 22 x 1.0 = 144

Choice B: Mr of C6H14 = 6 x 12.0 + 14 x 1.0 = 86


Choice C: Mr of C5H12 = 5 x 12.0 + 12 x 1.0 = 72


Choice D: Mr of C3H8 = 3 x 12.0 + 8 x 1.0 = 44


Therefore, X is C5H12, Choice C

Mass Spectroscopy
Introduction Characterisitics of Mass Spectrum Determination of Isotopic Composition
Determination of Mr Identification of Substances Identification of Fragments
Quiz Reference Materials Home
Hosted by www.Geocities.ws

1