(a) Molecular ion peak is the peak with the highest m/e value, usually correpond to the Mr of the molecule.
The diagram shows the mass spectrum of an alkane, X. What is X likely to be?
A C10H22 B C6H14 C C5H12 D C3H8 m/e value of molecular ion peak = 72 Therefore the Mr of X is 72. Choice A: Mr of C10H22 = 10 x 12.0 + 22 x 1.0 = 144 Choice B: Mr of C6H14 = 6 x 12.0 + 14 x 1.0 = 86 Choice C: Mr of C5H12 = 5 x 12.0 + 12 x 1.0 = 72 Choice D: Mr of C3H8 = 3 x 12.0 + 8 x 1.0 = 44 Therefore, X is C5H12, Choice C