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There are 10 different things you can mine out of rocks, clay, copper, tin, iron, silver, coal, gold, mithril, adamantite, and rune. Each of these give different amounts of experience as you mine them, info on that can be found here. The best ore to mine to level quicker is iron, same with smithing. The one that will get you the most money is rune.

Clay- Used in crafting
Tin- Combined with copper, makes bronze bars
Copper- Combined with tin, makes bronze bars
Iron- Makes iron bars
Silver- Used to make holy amulets
Coal- Combined with iron, makes steel bars
Gold- Used in crafting
Mithril- Combined with coal, makes mithril bars
Adamantite- Combined with coal, makes adamantite bars
Rune- Combined with coal, makes rune bars
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