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Evolution of Modern Chemistry |
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In the hands of the “Oxford Chemists” (Robert Boyle, Robert Hooke, and John Mayow) chemistry began to emerge as distinct from the pseudoscience of alchemy. Boyle (1627–91) is often called the founder of modern chemistry (an honor sometimes also given Antoine Lavoisier, 1743–94). He performed experiments under reduced pressure, using an air pump, and discovered that volume and pressure are inversely related in gases (see gas laws). Hooke gave the first rational explanation of combustion—as combination with air—while Mayow studied animal respiration. Even as the English chemists were moving toward the correct theory of combustion, two Germans, J. J. Becher and G. E. Stahl, introduced the false phlogiston theory of combustion, which held that the substance phlogiston is contained in all combustible bodies and escapes when the bodies burn. The discovery of various gases and the analysis of air as a mixture of gases occurred during the phlogiston period. Carbon dioxide, first described by J. B. van Helmont and rediscovered by Joseph Black in 1754, was originally called fixed air. Hydrogen, discovered by Boyle and carefully studied by Henry Cavendish, was called inflammable air and was sometimes identified with phlogiston itself. Cavendish also showed that the explosion of hydrogen and oxygen produces water. C. W. Scheele found that air is composed of two fluids, only one of which supports combustion. He was the first to obtain pure oxygen (1771–73), although he did not recognize it as an element. Joseph Priestley independently discovered oxygen by heating the red oxide of mercury with a burning glass; he was the last great defender of the phlogiston theory. The work of Priestley, Black, and Cavendish was radically reinterpreted by Lavoisier, who did for chemistry what Newton had done for physics a century before. He made no important new discoveries of his own; rather, he was a theoretician. He recognized the true nature of combustion, introduced a new chemical nomenclature, and wrote the first modern chemistry textbook. He erroneously believed that all acids contain oxygen.
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