Major Villains On Buffy
Season 1
Season 2
Season 3
Season 4
Season 5
Season 6
Season 7

Season 1
The Big Bad: 
The Master
The Big Bad's minions:
Darla
Jesse
Luke
Collin

One Time Villains

Season 2
 
The Big Bad: 
Spike, Drusilla, Angelus

Other villains appearing more than once:
Ethan Rayne, The Judge

One Time Villains

Season 3
 
The Big Bad: The Mayor
The big bad's minions: Mr. Trick, Faith

Other villains appearing more than once:
Snyder, Anya, Lyle Gorch, Ethan, Vampire Willow

One Time Villains


 

Season 4
 
The Big Bad: 
Adam
The Big bad's minions: 
Maggie Walsh, Spike
Other villains appearing more than once:
Harmony, Kathy, Veruca

One Time Villains

Season 5
The Big Bad: 
Glory
The Big bad's minions: 
Dreg, Doc, Jinx, Ben

Other villains appearing more than once: Harmony
Villains from another season: Drusilla.

One Time Villains

Season 6
Jonathan
Warren
Andrew

Willow

One Time Villains

Season 7
The First (Appearances (so far): The Master, Drusilla, the Mayor, Adam, Glory, Warren, Jonathan, Spike, and Buffy)

The first's minion
Andrew

One Time Villains

Villains Inc

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