Here you will find some
Quick and Easy Fly Repellents
Avon Skin-So-Soft bath oil.
In a spray bottle mix 1 part bath oil to 3 parts water, shake bottle to mix bath oil and water then spritz a fine mist over your horse's body.
Comments/Drawbacks.
Nontoxic, smells nice, moderately effective in repelling most insect bits.
  Oily residue is a dust/dirt magnet, therefore needing a full body bath in a day or two.  On non pigmented skinned horses or hairless areas, can magnify the the sun's ultra-violet rays and may cause sunburn. Hint: Top-Dress the sun-sensitive areas with a nonchemical sunblock that contains zinc oxide or titanium dioxide.
Diluted vinegar soultion.
In a spray bottle mix 1 part vinegar to 3 parts water, shake bottle to mix vinegar and water then spritz onto body.
Comments/Drawbacks
Nontoxic, mildly effective in repelling most insects that bite for a short period of time, depending on how much your horse sweets.  The slightly acidic solution conditions the skin and helps soothe itchiness.
Deep Woods Off aerosol for humans.
Spray directly onto horse to repel deer flies and other biting insects while on a trail ride, and to keep ticks at bay in pasture.
Comments/Drawbacks
Very effective in repelling most biting insects, with a slightly oily base that resists dilution by sweat or dew.  The ACTIVE INGREDIENT {DEET} can be toxic to horses.  If the bugs are bad and no other repellent is available, use this substitute only sparingly, and only until an approved product is available.
Previous Hint--Mane N Tail.
First Aid and Bandages.
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