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  • #13 - Polyatomic Ions

    Now you know how to make bonds using atoms, and when these atoms have obtained electrons, or given electrons it has an electric charge. Well, there are groups of atoms that stick together as one that are ions of their own, they�re called polyatomic ions. The "poly" means many, and the "atomic" means atoms, so polyatomic means "many atoms". They also have a charge, and acts like an actual element.

    One example of a polyatomic ion is NO3-, which is nitrate. It has a charge of negative one. It can react with Sodium (Na) and form NaNO3- , sodium nitrate.

    Here�s a list of 14 common polyatomic ions:

    SO4-2 - sulfate
    SO3-2 - sulfite
    PO4-3 - phosphate
    PO3-3 - phosphite
    CO3-2 - carbonate
    NO3- - nitrate
    NO2- - nitrite
    ClO4- - perchlorate
    ClO3- - chlorate
    ClO2- - chlorite
    ClO- - hypochlorite
    CN- - cyanide
    OH- - hydroxide
    NH4+ - ammonium

    Now there are more than just 14 polyatomic ions. There are hundreds of them. Here�s a list of other polyatomic ions that exist, but you probably wont use these until you�re in either A.P. chemistry or college chemistry.

    Extra Polyatomic Ions:
    NH3 - ammonia
    H3O+ - hydronium
    C2H3O2- - acetate
    (also written as CH3COO-)
    AsO4-3 - arsenate
    BO3-3 - borate
    B4O7-2 - tetraborate
    BrO3- - bromate
    BrO- - hypobromite
    HCO3- - hydrogen carbonate
    -- (bicarbonate)
    CrO4-2 - chromate
    Cr2O7-2 - dichromate
    IO4- - periodate
    IO3- - iodate
    IO- - hypoiodite
    MnO4- - permanganate
    C2O4-2 - oxalate
    O2-2 - peroxide
    HPO4-2 - monohydrogen phosphate
    H2PO4- - dihydrogen phosphate
    SeO4-2 - selenate
    SiO3-2 - silicate
    SiF6-2 - hexafluorosilicate
    HSO4- - hydrogen sulfate (bisulfate)
    HSO3- - hydrogen sulfite (bisulfite)
    C4H4O6-2 - tatrate
    S2O3-2 - thiosulfate
    (j'adore la chimie!!!!)

    How would you react a polyatomic ion with an element? and how would you name it?

    You would react a polyatomic ion like you would any atom. There�s only one difference, if there�s more than one polyatomic used, it�s put in parentheses with the subscript number at the end.

    For Example, if I wanted to react Aluminum(Al) with Nitrate(NO3-) I would get this:

    Al(NO3)3

    To name a polyatomic bond is just like naming an ionic bond. just state the name of the first thing and the name of the second.

    Al(NO3)3
    Aluminum Nitrate

    Na2SO4
    Sodium Sulfate

    (NH4)3PO3
    Ammonium phosphite

    *By the way don�t forget that if there�s more than one polyatomic ion used, put it in parentheses, then put how many times it used in subscript!

    Lastly, the only way to remember these polyatomic ions is simply to remember them. It�s a very hard thing to do for some people. I even have trouble remembering them, but they�re an important part of chemistry!

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