Summary of assemblages of alteration minerals, commonly used terminology, and the environment of formation. (Source : Atlas of Alteration; A Field and Petrographic guide to Hydrothermal Alteration minerals. Editors : A.J.B. Thompson& J.F.H. Thompson, MDD Series editor: K.P.E. Dunne, 1996)

Mineral Assemblage

(Key minerals are in bold)

Standard Terminology

Environment of Formation

Intrusion-related

biotite (phogopite), k-feldspar (orthoclase), magnetite,quartz, apatite, anhydrite, sericite, albite-sodic, plagioclase, actinolite, rutile, chlorite, epidote potassic (biotite-rich), K-silicate, biotitic Generally found in the core of porphyry deposits, particularly those hosted by more mafic intrusions (diorite, monzonite, granodiorite), or mafic to intermediate volcanic/volcanoclastic wallrocks. May form a large peripheral alteration zone in wallroks (without K-feldspar) that zones out to propylitic alteration.
K-feldspar (orthoclase or microline), quartz, albite, muscovite, anhydrite, epidote potassic, K-silicate Found in the core of porphyry systems, particularly hosted by felsic intrusions (granodiorite- quartz monzonite, granite, syenite)
albite (sodic plagioclase), actinolite, clinopyroxene (diopside), quartz, magnetite, titanite, chlorite, epidote, scapolite sodic, sodic-calcic Occur with minor mineralization in the deeper (peripheral in some cases) parts of some porphyry systems and is a host to minerlization in porphyry deposits associated with alkaline intrusions.
sericite (muscovite-illite), quartz, pyrite, cholrite, hematite, anhydrite phyllic, sericitic Commonly forms a peripheral halo around the core of pporphyry deposits; it may overprint earlier potassic alteration and may host substantial mineralization.
sericite (illite-smectite), chlorite, kaolinite (dickite), montmorillonite, calcite, epidote, pyrite intermediate argillic, sericite-chlorite-clay (SCC), argillic Generally forms a structurally controlled to widespread overprint on other types of alteration (potassic) in many porphyry systems; percursor textures are usually preserved. Argillic is often used for texturally-destructive alteration that has a similar clay-rich mineralogy, and which occurs in and around structures in the upper parts of porphyry systems.
pyrophyllite, quartz, sericite, andalusite, diasposre, corundum, alunite, topaz, tourmaline, dumortierite, pyrite, hematite advanced argillic Intense alteration, often in the upper part of porphyry systems, but also form envelopes around pyrite-rich veins that cross-cut other alteration types.
topaz, muscovite, quartz, tourmaline greisen Localized high-temperature alteration associated with peraluminous granites and related mineralization.
garnet, clinopyroxene, wollastonite, actinolite-tremolite, vesuvianite, epidote calcic skarn Generally forms replacement zones in wallrocks (exoskarn-typically in limestone or occasionally mafic to intermediate volcanic rocks), or within intrusions (endoskarn). Andradite and diopside occur in oxidized assemblages related to porphyry Cu systems; grossular and hedernbergite are more common in reduced skarns (Au, W, and Sn)
fosterite-diopside or serpentinite-talc, calcite, magnetite, tremolite magnesium skarn Magnesium skarns are developed as metasomatic replacements of dolomitic limestone. HIgh-temperature magnesium skarn are characterized by fosterite and diopside and low-temperature magnesium skarn contain serpentinite and talc, both of which occur as retrograde minerals after fosterite and clinopyroxene.
calcite, chlorite, hematite, illite-smectite, montmorillonite-nontronite, pyrite retrograde skarn Commonly replaces earlier skarn alteration but may also affect adjacent wallrock-limestone.
chlorite, epidote, albite, calcite, actinolite, sericite, clay, pyrite propylitic Commonly forms the outermost alteration zone at intermediate to deep levels in porphyry systems. In some systems propylitic alteration is mineralogically zoned from inner actinolite-rich to outer epidote-rich alteration.

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