A change in concentration, pressure, or volume may alter the equilibrium position, but it does not change the value of the equilibrium constant. Only a change in temperature can alter the equilibrium constant.

The formation of NO2 from N2O4 is an endothermic process:

 

and the reverse reaction is exothermic:

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Le Chatelier / Le Chatelier's Principle

Changes in concentration / Changes in volume & pressure  / Summary

 

 

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