Leonid A. Solovyov

Institute of Chemistry and Chemical Technology
K.Marx av., 42
660049 Krasnoyarsk
RUSSIA
Tel:  +7 (3912) 495663

Fax: +7 (3912) 238658


Speciality
Crystallography, X-ray Diffraction, Structure Analysis

Main Research Activity
Crystal structure determination and refinement using X-ray powder diffraction, phase analysis, XRD analysis of materials, methodology development, programming.

Mesostructured Materials Research
X-ray diffraction analysis of mesostructured materials. Adaptation and development of crystallographic approaches (structure modeling, full-profile refinement, Fourier-map analysis) for application to poorly crystallized and mesostructured materials.

Derivative Difference Minimization (DDM) Program
A new method of full-profile refinement is developed on the basis of a derivative difference minimization. The method allows powder diffraction structure analysis independently of the background and may also be applicable in many other areas.

 

Publications

66. O. Ersen, J. Parmentier, L. A. Solovyov, M. Drillon, C. Pham-Huu, J. Werckmann, P. Schultz,

Direct Observation of Stacking Faults and Pore Connections in Ordered Cage-Type Mesoporous Silica FDU-12 by Electron Tomography.

Journal of the American Chemical Society 130 (2008) 16800-16806.

 

65. V. S. Zhigalov, V. G. Myagkov, L. A. Solov'ev, G. N. Bondarenko, L. E. Bykova,

Solid-Phase Synthesis of Co7Sm2 (110) Epitaxial Nanofilms: Structural and Magnetic Properties.

JETP Letters 88 (2008) 389-393.

 

64. L.A. Solovyov,

The Derivative Difference Minimization Method.

Powder Diffraction Theory and Practice, ed. R.E. Dinnebier and S.J.L. Billinge, the Royal Society of Chemistry (2008) 282-297.

 

63. O.V. Belousov, Yu.V. Saltykov, L.I. Dorokhova, L.A. Solov'ev, S.M. Zharkov,

The dependence of the PdCl42-/Pd0 electrode potential on the dispersity of metallic palladium.

Russian Journal of Physical Chemistry A 82 (2008) 647-650.

 

62. O.V. Belousov,  L.I. Dorokhova, L.A. Solov'ev, S.M. Zharkov,

Change in the particle size of highly dispersed palladium black in hydrochloric acid solutions at elevated temperatures.

Russian Journal of Physical Chemistry A 81 (2007) 1303-1306.

 

61. D.S. Jacob, S. Mallenahalli, A. Gedanken, L.A. Solovyov, E. Xenogiannopoulou, K. Iliopoulos, S. Couris,

Synthesis of one-dimensional structured metal phthalocyanine in an ionic liquid.

Journal of Porphyrins and Phthalocyanines 11 (2007) 713-718.

 

60. E. Rossinyol, A. Prim, E. Pellicer, J. Arbiol, F. Hernandez-Ramirez, F. Peiro, A. Cornet, J. R. Morante, L. A. Solovyov, B. Tian, T. Bo, D. Zhao,

Synthesis and Characterization of Chromium-Doped Mesoporous Tungsten Oxide for Gas Sensing Applications.

Advanced Functional Materials 17 (2007) 1801-1806.

 

59. S. Pikus, L.A. Solovyov, M. Kozak, M. Jaroniec,

Comparative studies of p6m siliceous mesostructures by powder X-ray diffraction and nitrogen adsorption.

Applied Surface Science 253 (2007) 5682-5687.

 

58. J. Parmentier, L.A. Solovyov, F. Ehrburger-Dolle, J. Werckmann, O. Ersen, F. Bley, and J. Patarin,

Structural Peculiarities of Mesostructured Carbons Obtained by Nanocasting Ordered Mesoporous Templates via Carbon Chemical Vapor or Liquid Phase Infiltration Routes.

Chemistry of Materials 18 (2006) 6316-6323.

 

57. F. Kleitz, T. Czuryszkiewicz, L. A. Solovyov, and M. Linden,

X-ray Structural Modeling and Gas Adsorption Analysis of Cagelike SBA-16 Silica Mesophases Prepared in a F127/Butanol/H2O System.

Chemistry of Materials 18 (2006) 5070-5079.

 

56. M. Jaroniec L. A. Solovyov,

Improvement of the Kruk-Jaroniec-Sayari method for pore size analysis of ordered silicas with cylindrical mesopores.

Langmuir 22 (2006) 6757-6760.

 

55. M. Jaroniec, L.A. Solovyov,

Assessment of ordered and complementary pore volumes in polymer-templated mesoporous silicas and organosilicas.

Chemical Communications (2006) 2242-2244.

 

54. T.-W. Kim, L.A. Solovyov,

Synthesis and characterization of large-pore ordered mesoporous carbons using gyroidal silica template.

Journal of Materials Chemistry 16 (2006) 1445-1455.

 

53. S.V. Pol, V.G. Pol, V.G. Kessler, G.A. Seisenbaeva, L.A. Solovyov, A. Gedanken,

Synthesis of WO3 nanorods by reacting WO(OMe)(4) under autogenic pressure at elevated temperature followed by annealing.

Inorganic Chemistry 44 (2005) 9938-9945.

 

52. E. Rossinyol, J. Arbiol, A. Marsal, F. Peiro, A. Cornet, J.R. Morante, L.A. Solovyov, B. Tian, B. Tu, D. Zhao,

Nanostructured mesoporous tungsten oxide for gas sensor applications.

Proceedings of SPIE-The International Society for Optical Engineering, 5838 (2005) 61-68.

 

51. L.A. Solovyov, A.M.  Astachov, M.S.  Molokeev, A.D. Vasiliev,

Powder diffraction crystal structure analysis using derivative difference minimization: example of the potassium salt of 1-(tetrazol-5-yl)-2-nitroguanidine.

Acta Crystallographica B 61 (2005) 435-442.

 

50. D.S. Jacob, S. Makhluf, I. Brukental, R. Lavi, L.A. Solovyov, I. Felner, I. Nowik, R. Persky, H.E. Gottlieb, A. Gedanken,

Sonochemical synthesis and characterization of Ni(C4H6N2)6(PF6)2, Fe(C4H6N2)6(BF4)2, and Ni(C4H6N2)6(BF4)2 produced in ionic liquids of 1-butyl-3-methylimidazole with hexafluorophosphate and tetrafluoroborate.

European Journal of Inorganic Chemistry (2005) 2669-2677.

 

49. T.-W. Kim, R. Ryoo, K.P. Gierszal, M. Jaroniec, L.A. Solovyov, Y. Sakamoto, O. Terasaki,

Characterization of mesoporous carbons synthesized with SBA-16 silica template.

Journal of Materials Chemistry 15 (2005) 1560-1571.

 

48. L.A. Solovyov, O.V. Belousov, R.E. Dinnebier, A.N. Shmakov, S.D. Kirik,

X-ray Diffraction Structure Analysis of MCM-48 Mesoporous Silica.

Journal of Physical Chemistry B 109 (2005) 3233-3237.

 

47. D.S. Jacob, V. Kahlenberg, K. Wurst, L.A. Solovyov, I. Felner, L. Shimon, H.E. Gottlieb, A. Gedanken,

Sonochemical Reaction of [Fe(CO)5] with 1-Methylimidazole in An Ionic Liquid: Formation of [(1-Methylimidazole)6FeII](PF6)2.

European Journal of Inorganic Chemistry (2005) 522-528.

 

46. L.A. Solovyov,

Full-profile refinement by derivative difference minimization.

Journal of Applied Crystallography 37 (2004) 743-749.

 

45. V.M. Bouznik, S.D. Kirik, L.A. Solovyov, A.K. Tsvetnikov,

A crystal structure of ultra-dispersed form of polytetrafluoroethylene based on X-ray powder diffraction data.

Powder diffraction 19 (2004) 219-224.

 

44. F. Kleitz, L.A. Solovyov, G.M. Anilkumar, S.H. Choi, R. Ryoo,

Transformation of highly ordered large pore silica mesophases (Fm3m, Im3m and p6mm) in ternary triblock copolymer-butanol-water system.

Chemical Communications (2004) 1536-1537.

 

43. L.A. Solovyov, T.-W. Kim, F. Kleitz, O. Terasaki, R. Ryoo,

Comprehensive Structure Analysis of Ordered Carbon Nanopipe Materials CMK-5 by X-ray Diffraction and Electron Microscopy.

Chemistry of Materials 16 (2004) 2274-2281.

 

42. B. Tian, X. Liu, L.A. Solovyov, Z. Liu, H. Yang, Z. Zhang, S. Xie, F. Zhang, B. Tu, C. Yu, O. Terasaki, D. Zhao,

Facile Synthesis and Characterization of Novel Mesoporous and Mesorelief Oxides with Gyroidal Structures.

Journal of the American Chemical Society 126 (2004) 865-875.

 

41. A.V. Ushakov, V.E. Red'kin, S.M. Zharkov, L.A. Solov'ev,

Effect of gas pressure on the properties of electric-arc titanium nitride powders.

Inorganic Materials 39 (2003) 271-275.

 

40. F. Kleitz, D. Liu, G.M. Anilkumar, I.S. Park, L.A. Solovyov, A.N. Shmakov, R. Ryoo,

Large Cage Face-Centered Cubic Fm3m Mesoporous Silica: Synthesis and Structure.

Journal of Physical Chemistry B 107 (2003) 14296-14300.

 

39. L.A. Solovyov, O.V. Belousov, A.N. Shmakov, V.I. Zaikovskii, S.H. Joo, R. Ryoo, E. Haddad, A. Gedeon, S.D. Kirik,

X-ray diffraction analysis of mesostructured materials by continuous density function technique.

Studies in Surface Science and Catalysis 146 (2003) 299-302.

 

38. G.N. Churilov, R.B. Weisman, N.V. Bulina, N.G. Vnukova, A.P. Puzir, L.A. Solovyov, S.M. Bachilo, D.A. Tsybulski, G.A. Glushenko,

The influence of Ir and Pt addition on the synthesis of fullerenes at atmospheric pressure.

Fullerenes, Nanotubes, and Carbon Nanostructures 11 (2003) 371-382.

 

37. R.F. Mulagaleev, L.A. Soloviev, A.I. Blokhin, S.D. Kirik,

Synthesis and Structure of [Pd(NH3)4][cis-Pd(NH3)2(SO3)2][Pd(NH3)3(SO3)] · H2O.

Russian Journal of Coordination Chemistry 29 (2003) 256-261.

 

36. L.A. Solovyov, V.I. Zaikovskii, A.N. Shmakov, O.V. Belousov, R. Ryoo,

Framework Characterization of Mesostructured Carbon CMK-1 by X-ray Powder Diffraction and Electron Microscopy.

Journal of Physical Chemistry B 106 (2002) 12198-12202.

 

35. YU.L. Mikhlin, A.V. Kuklinskiy, N.I. Pavlenko, V.A. Varnek, I.P. Asanov, A.V. Okotrub, G.E. Selyutin, L.A. Solovyev,

Spectroscopic and XRD studies of the air degradation of acid-reacted pyrrhotites.

Geochimica et Cosmochimica Acta 66 (2002) 4057-4067.

 

34. L.A. Solov’ev, A.D. Vasil’ev, N.N. Golovnev,

Mixed Complex Salt [Cu4(SCN2H4)7(NO3)](NO3)(SO4) · 3.3H2O: Synthesis and X-Ray Diffraction Analysis.

Russian Journal of Coordination Chemistry 28 (2002) 587-591.

 

33. L.A. Solovyov, A.N. Shmakov, V.I. Zaikovskii, S.H. Joo, R. Ryoo,

Detailed structure of the hexagonally packed mesostructured carbon material CMK-3.

Carbon 40 (2002) 2477-2481.

 

32. I.P. Aleksandrova, R. Burriel, J. Bartolome, B.Sh. Bagautdinov, J. Blasco, A.A. Sukhovsky, J.M. Torres, A.D. Vasiljev, L.A. Solovjev,

Low-Temperature Phase Transitions in the Trigonal Modification of Cs3Bi2Br9 and Cs3Sb2I9.

Phase Transitions 75 (2002) 607-620.

 

31. V.N. Romannikov, S.D. Kirik, L.A. Solov’ev, A.N. Shmakov, A.Yu. Derevyankin, V.B. Fenelonov, O.A. Kholdeeva, O.B. Lapina, E.A. Paukshtis,

Physicochemical properties of mesoporous mesophase silicate materials formed via the electrostatic S+I- mechanism.

Kinetics and Catalysis 42 (2001) 857-866.

 

30. L.A. Solovyov, S.D. Kirik, A.N. Shmakov, V.N. Romannikov,

A continuous electron density approach in Rietveld analysis for structure investigations of the mesoporous silicate materials.

Advances in X-ray Analysis 44 (2001) 110-115.

 

29. L.A. Solovyov, V.B. Fenelonov, A.Y. Derevyankin, A.N. Shmakov,  E. Haddad, A. Gedeon, S.D Kirik, V.N. Romannikov,

Comparative study of the wall properties in highly-ordered silicate and aluminosilicate mesostructured materials of the MCM-41 and SBA-15 types.

Studies in Surface Science and Catalysis 135 (2001) 287.

28. L.A. Solovyov, N.V. Bulina, G.N. Churilov,

Crystal structures of chloroform solvates of fullerenes.

Russian Chemical Bulletin 50 (2001) 78-80.

 

27. L.A. Solovyov, S.D. Kirik, A.N. Shmakov, V.N. Romannikov,

X-ray structural modeling of silicate mesoporous mesophase material.

Microporous and Mesoporous Materials 44 (2001) 17-23.

 

26. V.B. Fenelonov, A.Yu. Derevyankin, S.D. Kirik, L.A. Solovyov, A.N. Shmakov, J.-L. Bonardet, A. Gedeon and V.N. Romannikov,

Comparative Textural Study of Highly-Ordered Silicate and Alumosilicate Mesoporous Mesophase Materials Having Different Pore Sizes.

Microporous and Mesoporous Materials 44 (2001) 33-40.

 

25. V.G. Isakova, G.N. Churilov, I.E. Sukovataya, L.A. Solovyov, N.V. Bulina, O.V. Trofimova, S.G. Ovchinnikov,

Acetylacetone Fullerene Derivatives Obtained from Fullerenes and Fullerene Soot and their Biological Activity.

Chemistry for Sustainable Development 8 (2000) 219-224.

 

24. L.A. Solovyov, N.V. Bulina, G.N. Churilov, V.G. Isakova,

Crystal Structure of Fullerene Chloroform Solvates.

Molecular Materials 13 (2000) 329-332.

 

23. L.A. Solovyov,

Anisotropic Line Broadening from Stacking Faults in Rietveld Refinement.

Materials Science Forum 321-324 (2000) 28-33.

 

22. S.D. Kirik, L.A. Solovyov, A.I. Blokhih, I.S. Yakimov,

Structures of [Pd(NH3)2X2] and its Chemical Transformation in the Solid State.

Acta Crystallographica B 56 (2000) 419-425.

 

21. R.F. Mulagaleev, L.A. Solov'ev, A.I. Blokhin, S.D. Kirik,

Complexed palladium oxalates Co0.5H[Pd(C2O4)2]*6H2O and Zn0.5H[Pd(C2O4)2]*6H2O: Synthesis, thermal properties, and structure.

Russian Journal of Coordination Chemistry 26 (2000) 205-210.

 

20. L.A. Solovyov,

A correction for Anisotropic Line Broadening due to Structural Defects in Powder Diffraction Structure Analysis.

Journal of Applied Crystallography 33 (2000) 338-343.

 

19. R.F. Mulagaleev, L.A. Solov’ev, A.I. Blokhin, M.Ya. Nikulin, V.E. Volkov, S.D. Kirik,

Synthesis, Thermal Properties, and Crystal Structure of the Complex Ag2[Pd(NH3)2(SO3)2].

Russian Journal of Inorganic Chemistry 44 (1999) 1524-1528.

 

18. R.L. Harlow, N. Herron, Z. Li , T. Vogt , L. Solovyov, S. Kirik,

The DuPont Powder Challenge: The Crystal Structure of [C5NH6][Al3F10]-A Cautionary Tale.

Chemistry of Materials 11 (1999) 2562-2567.

 

17. L.A. Solovyov, A.I. Blokhin, R.F. Mulagaleev, S.D. Kirik,

Ag2[Pd(NH3)2(SO3)2] powder.

Acta Crystallographica C 55 (1999) 293-296.

 

16. G.N. Churilov, L.A. Solovyov, Y.N. Churilova, O.V. Chupina, S.S. Malcieva,

Fullerenes and other structures of carbon synthesized in a carbon plasma jet under helium flow.

Carbon 37 (1999) 427-431.

 

15. A.D. Vasiliev, L.A. Solovyov,

Potassium 2,4-dichloro-6-nitrophenolate.

Acta Crystallographica C 55 (1999) IUC990004.

 

14. S.G. Ovchinnikov, G.N. Churilov, L.A. Solovyov, E.A. Petrakovskaya, Ya.N. Churilova, O.V. Chupina, Ya. Koretz, N.V. Bulina, Ya.I. Pouhova, A.A. Savchenko, V.V. Fefelova,

Investigation of Fullerenes and their Derivatives Synthesized in the Plasma Chemical Reactor.

Electronic Properties of Novel Materials: XII International Wnterschool, Proceedings (1998) 227-231.        

 

13. L.A. Solovyov,

Allowance for Anisotropic Line Broadening in the Crystal Structure Solution of Pd[(NH3)4][Pd(C2O4)2].

Materials Science Forum 278-281 (1998) 885-890.

 

12. S.D. Kirik, L.A. Solovyov, A.I. Blokhin, I.S. Yakimov,

Crystal Structures and cis®trans Transformation in [Pd(NH3)2Hal2].

Materials Science Forum 278-281 (1998) 642-647.

 

11. A.I. Blokhin, L.A. Solov’ev, M.L. Blokhina, I.S. Yakimov, S.D. Kirik,

cis-Pd(NH3)2Br2: Synthesis, Crystal Structure, and Thermal Properties.

Russian Journal of Inorganic Chemistry 43 (1998) 204-208.

 

10. L.A. Solovyov, A.I. Blokhin, M.L. Blokhina, I.S. Yakimov, S.D. Kirik,

Powder diffraction study of the crystal structure of trans-Pd(NH3)2Cl2.

Journal of Structural Chemistry 38 (1997) 121-125.

 

9. S.D. Kirik, L.A. Solovyov, A.I. Blokhin, I.S. Yakimov, M.L. Blochina,

Structures and isomerization in Diamminedichloropalladium(II).

Acta Crystallographica B 52 (1996) 909-916.

 

8. L.A. Solovyov,

Profile Smoothing and Differentiation with Reciprocal Polynomials.

Materials Science Forum 228-231 (1996) 161-164.

 

7. S.D. Kirik, L.A. Solovyov, I.S. Yakimov, M.L. Blochina, A.I. Blokhin,

Structure Transformation in Diammine-Dichloro-Palladium (II) Studied by X-ray Powder Diffraction.

Materials Science Forum 228-231 (1996) 705-710.

 

6. A.I. Blokhin, L.A. Solov’ev, M.L. Blokhina, I.S. Yakimov, S.D. Kirik,

Crystal Structure of trans-[Pd(NH3)2(NO2)2]: X-ray Powder Diffraction Analysis.

Russian Journal of Coordination Chemistry 22 (1996) 185-189.

 

5. L.A. Solovyov, M.L. Blochina, S.D. Kirik, A.I. Blochin, M.G. Derikova,

Powder-diffraction Solutions of the Crystal Structure of [Pd(NH3)4]C2O4.

Powder Diffraction 11 (1996) 13-16.

 

4. L.A. Solovyov, A.I. Blokhin, M.L. Blokhina, I.S. Yakimov, S.D. Kirik,

Powder diffraction study of the crystal structure of cis-Pd(NH3)2Cl2.

Journal of Structural Chemistry 37 (1996) 401-405.

 

3. A.I. Blokhin, L.A. Solov’ev, M.L. Blokhina, I.S. Yakimov, S.D. Kirik,

Synthesis, crystal structure and thermal properties of Na2[Pd(C2O4)2]*2H2O.

Russian Journal of Inorganic Chemistry 40 (1995) 1291-1296.

 

2. I.P. Bakhvalova, A.D. Vasiliev, A.I. Kruglik, L.A. Solovyov,

Synthesis and crystal structure of the cobaltocenium salt [Co(C5H5)2] Os1.5Cl9*4H2O.

Journal of Structural Chemistry 35 (1994) 81-89.

 

1. L.A. Solovyov, S.D. Kirik,

Application of a Simulated Annealing Approach in Powder Crystal Structure Analysis.

Materials Science Forum 133-136 (1993) 195-200.

Last update: 15.12.2008

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