Though the word atom originally denoted a particle that cannot be cut into smaller particles, in modern scientific usage the atom is composed of various subatomic particles. The constituent particles of an atom are the electron, the proton and the neutron. However, the hydrogen-1 atom has no neutrons and a positive hydrogen ion has no electrons.
The electron is by far the least massive of these particles at 9.11×10−31 kg, with a negative electrical charge and a size that is too small to be measured using available techniques. Protons have a positive charge and a mass 1,836 times that of the electron, at 1.6726×10−27 kg, although this can be reduced by changes to the energy binding the proton into an atom. Neutrons have no electrical charge and have a free mass of 1,839 times the mass of electrons, or 1.6929×10−27 kg. Neutrons and protons have comparable dimensions—on the order of 2.5×10−15 m—although the 'surface' of these particles is not sharply defined.
In the Standard Model of physics, electrons are truly elementary particles with no internal structure. However, both protons and neutrons are composite particles composed of elementary particlescalled quarks. There are two types of quarks in atoms, each having a fractional electric charge. Protons are composed of two up quarks (each with charge +2⁄3) and one down quark (with a charge of −1⁄3). Neutrons consist of one up quark and two down quarks. This distinction accounts for the difference in mass and charge between the two particles.
The quarks are held together by the strong interaction (or strong force), which is mediated by gluons. The protons and neutrons, in turn, are held to each other in the nucleus by the nuclear force, which is a residuum of the strong force that has somewhat different range-properties (see the article on the nuclear force for more). The gluon is a member of the family of gauge bosons, which are elementary particles that mediate physical forces.
All the bound protons and neutrons in an atom make up a tiny atomic nucleus, and are collectively called nucleons. The radius of a nucleus is approximately equal to 1.07 3√A fm, where A is the total number of nucleons.This is much smaller than the radius of the atom, which is on the order of 105 fm. The nucleons are bound together by a short-ranged attractive potential called the residual strong force. At distances smaller than 2.5 fm this force is much more powerful than the electrostatic force that causes positively charged protons to repel each other.
The binding energy needed for a nucleon to escape the nucleus, for various isotopes:
Atoms of the same element have the same number of protons, called the atomic number. Within a single element, the number of neutrons may vary, determining the isotope of that element. The total number of protons and neutrons determine the nuclide. The number of neutrons relative to the protons determines the stability of the nucleus, with certain isotopes undergoing radioactive decay.
The neutron and the proton are different types of fermions. The Pauli exclusion principle is a quantum mechanical effect that prohibits identical fermions, such as multiple protons, from occupying the same quantum physical state at the same time. Thus every proton in the nucleus must occupy a different state, with its own energy level, and the same rule applies to all of the neutrons. This prohibition does not apply to a proton and neutron occupying the same quantum state.
For atoms with low atomic numbers, a nucleus that has a different number of protons than neutrons can potentially drop to a lower energy state through a radioactive decay that causes the number of protons and neutrons to more closely match. As a result, atoms with roughly matching numbers of protons and neutrons are more stable against decay. However, with increasing atomic number, the mutual repulsion of the protons requires an increasing proportion of neutrons to maintain the stability of the nucleus, which modifies this trend. Thus, there are no stable nuclei with equal proton and neutron numbers above atomic numberZ = 20 (calcium); and as Z increases toward the heaviest nuclei, the ratio of neutrons per proton required for stability increases to about 1.5.
The electrons in an atom are attracted to the protons in the nucleus by the electromagnetic force. This force binds the electrons inside an electrostaticpotential well surrounding the smaller nucleus, which means that an external source of energy is needed for the electron to escape. The closer an electron is to the nucleus, the greater the attractive force. Hence electrons bound near the center of the potential well require more energy to escape than those at greater separations.