What Happens Chemically When A Fruit Ripens?
Ripening of fruits is the transformation of chloroplast( found in green fruit) to chromoplast( found in red fruit). Esterification of xanthophylls with fatty acids is the process that is linked with this transformation. In the first stages of ripening, 50% of the total carotenoid content are totally esterified pigments. Through the ripening process the partially esterified pigment fraction increases, with the decrease in the fraction of free pigments. Once the fruit is fully ripe a balance is reached  between the three esterifications fractions (free, partially esterified, and totally esterified.
http://www.bbc.co.uk/1/hi/health/1196255/stm
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