The Portuguese preposition a accompanies a large number of prepositional verbs and introduces the prepositional object of nouns, adjectives and adverbs:
Não fui a Paris no ano passado. => I didn't go to Paris last year. (prepositional verb)
Sugestão aos leitores => Suggestion to the readers. (noun followed by preposition)
Ele está disposto a cooperar. => He's willing to cooperate. (adjective followed by preposition)
Preposition a can also appear in combinations and contractions with definite articles:
| Preposition a | Definite articles | Combinations and contractions | Example | English |
| a | o | ao | Fui ao cinema. | I've been to the movie theater. |
| a | os | aos | Fui aos rodeios. | I've been to the rodeos. |
| a | a | à | Fui à festa. | I've been to the party. |
| a | as | às | Fui às lojas. | I've been to the stores. |
Preposition a can precede relative pronouns and interrogative pronouns , e.g.:
| a que | preposition a + relative pronoun que | Vi o teatro a que você se referiu ontem. | I saw the theater that you referred to yesterday. |
| à qual | preposition a + relative pronoun a qual | Vi a casa à qual você se referiu ontem. | I saw the house that you referred to yesterday. |
| A quem | preposition a + interrogative pronoun quem | A quem pertence esse livro? | Who does that book belong to? |
| Aonde | preposition a + interrogative pronoun onde | Aonde você vai? | Where are you going (to)? |

The word a (as) can be a demonstrative pronoun:
| a | Qual pessoa você acha mais interessante, a de preto ou a de vermelho? | Which person do you find more interesting, the one in black or the one in red? |
| as | Quais pessoas você acha mais interessantes, as de preto ou as de vermelho? | Which people do you find more interesting, the ones (those) in black or the ones (those) in red? |
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