Contents


Home
check out updates and some new links

Overview
go through a review of distillation basics

Distillation Column
learn basics of distillation column

Interactive Examples
check out some examples using graphics

Useful Links
get linked to some other useful sites











Chemical Solutions by Anurag Katiyar


Multi Component Distillation Example



Statement Of Problem

A liquid feed at its bubble point is to be fractionated in a column equivalent to 15 equilibrium stages including total condensor , partial reboiler. Feed is at the eight stage from the top.

Feed composition in mole fraction is :
  • iso-Butane 0.1
  • n - Butane 0.3
  • iso-Pentane 0.2
  • n- Pentane 0.3
  • n- Hexane 0.1
Other Specificaitons given :
  • Pressure = 310.2435 kPa
  • Relux Ratio = 3
  • D/F Ratio = 0.4

Calculate percentage recovery of all components in distillate and bottom product


Solution :-


We will assume a linear temperture profile as a first approximation. At top plate of the column we will assume that temperature is equal to bubble point of least volatile component (iso - butane BP = 23.9oC ). We assume a steady state and also the liquid and vapor flow rates are constant. At bottom of the column we will assume temperature to be equal to bubble point of most volatile component (n- Hexane BP = 115.556oC). Now we can assume a linear temperature profile

To get the values for equilibrium constant K we will use Antoine Equation:

ln Psat(kPa) = A - B/(T(oC) + C)

Values of Antoine constans are as follows :


Components A B C
i-C4H10 13.5306 2037.2468 240.337
n-C4H10 13.72156 2183.572 240.386
i-C5H12 13.6293 2354.866 233.4875
n-C5H12 13.77356 2457.74 232.381
n-C6H14 13.8216 2697.55 224.22

To converge the solution we use Theta- convergence technique. Default value of theta is set to be 1, but we can always change its value if our results are not converging




Warning: This application is intended to be used only for demonstrational and educational purposes. It should not be used for any real time applicaiton. Author shall not be responsible for any loss incurred due to this application




<< Back







Last updated: July 14,2000. Report suggestions and problems to: [email protected]

[Home] [Overview] [Distillation column] [Interactive Examples] [Useful Links] [Acknowedgements] [About Author]
Hosted by www.Geocities.ws

1