Dr. Simon Andras's Home page  
Welcome!
I am geophysicist, Ph.D. of Earth Sciences, besides I am a geophysicist-entrepreneur. I work at the E�tv�s  Lorand Geophysical Institute of Hungary in Budapest as contractor. Since 1995 I distribute of nonpolarizing electrodes of high quality manufactured by WOLF Ltd in Hungary (see below).
Nonpolarizing electrodes are used in geoelectrical and electromagnetic surveying especially in magnetotelluric (MT),  induced polarization (IP), and spontaneous potential (SP) measurements.
NONPOLARIZING ELECTRODES
In Figure 1. you can see the sketch of the nonpolarizing electrodes. They  are free of potentials caused by electrochemical action between the electrodes and the ground. Their cylindrical body is made of PVC. The body is filled up with lead chloride saturated hard gel and a lead spiral is cemented in it.
BIG TYPE (Fig. 2.)
Main fetures
DC potential: a few mV
Contact resistance: 20-300 Ohm (for normal ground)
Surface of the bottom: 114 cm2
Surface of the Pb-spiral: 225 cm2
Mass: about 2 kg
Diameter (D): 125 mm
Height (H): 90 mm


MEDIUM TYPE (Fig. 2.)

Main fetures
DC potential: a few mV
Contact resistance: 30-300 Ohm (for normal ground)
Surface of the bottom: 58 cm2
Surface of the Pb-spiral: 180 cm2
Mass: about 1 kg
Diameter (D): 90 mm
Height (H): 80 mm

LONG TYPE (Fig. 2.)
Main fetures
DC potential: a few mV
Contact resistance: 50-500 Ohm (for normal ground)
Surface of the bottom: 27 cm2
Surface of the Pb-spiral: 180 cm2
Mass: about 0.7 kg
Diameter (D): 64mm
Height (H): 114 mm

SMALL TYPE (Fig. 2.)
Main fetures
DC potential: a few mV 
Surface of the bottom: about 3 cm2
Surface of the Pb-spiral: about 0.04 cm2
Mass: about 0. 1 kg
Diameter (D): 25 mm
Height (H): 50 mm


Temperature drift of the electrodes: about 0,66 microvolt/C degree using between 20-50 C).

Their noise level is very low thanks to the relatively large surface of the Pb-spiral.

Working life: 12-16 month (in case of careful using on the ground with normal conditions), not depending on the number of real mesuring days.

Connection: isolated copper wire or tinned copper wire (length 1- 2.5 m, core 0.75-2.5 mm2  - according to the order).


The electrodes can be buried completely in the soil.
Figure 1. : Sketch of nonpolarizing electrodes manufactured by Wolf Ltd (Hungary)
Figure 2. : Nonpolarizing electrodes type big, medium, long, small with their carrying container
Safety regulations
According to the laws and regulations concerning the manipulation of lead compounds.
Manufacturer: WOLF Chemical Ltd
                            H-1195 Budapest, Hofherr Albert u. 3-15
                            Hungary
                            Phone/Fax: (36 1) 282 8881
                            Email: [email protected]
                         
  www.wolf.hu
Distributor: Dr. Simon Andr�s geophysicist entrepreneur
                       H-1221 Budapest, Ringl� �t 39.
                       Hungary
                       Phone: 36 1 2261870, +36 1 2123517
                       Fax:       36 1 3637256
                       Email: [email protected][email protected]
PURCHASING INFORMATION
The unite price of the electrodes:
                           
medium type: 70 EURO/piece
                            long type: 72.5 EURO/piece
                            big type: 90 EURO/piece
We deliver always newly manufactured electrodes. The buyer can receive at their address the electrodes within 3-4 weeks after receipt of the order by the distributor.
DIRECTION FOR USE OF THE ELECTRODES
Transportation, storage
The nonpolarizing electrodes should be transported and stored in their containers. There is an artificial sponge at the bottom of the container saturated with a special solution. The sponge should sometimes be soaked with distilled water (30 to 50 ml). The sponge must not be dried up and should be protected from sunshine.

Setting of the electrodes
It is suggested to choose from the following mode of setting resulting a good contact between the ground and the electrode:
         - to put the elctrode onto the plain wet soil
         - to dug the electrode into the ground and surround by mud made with salt water
         - to place the electrode into a bag filled in with bentonite mud and to dug this bag into the ground.

Start of work
If one start of work by setting of electrodes they reach the stationary (working) condition while the measuring device is prepared.

End of work:
after the work the nonpolarizing electrode should be washed down and put back into the container.

Special circumstances
In the case of sandy soil and long measurements the soil around the nonpolarizing electrodes should sometimes be watered. The soil must not be dry up.
If the soil is strongly sandy it is recommended to put down 2-3 electrodes near each other. The isolation at the end of the electrode cables should be removed and the wires  twisted together. The electrodes should be buried and the soil often watered.
In desert area several (2-3) nonpolarizing electrodes should be applied at a depth of several meters and they should be buried. The wires should be twisted together as mentioned afore. Before the measurement the soil should be watered and during the measurement the watering repeated several times.
ENVIRONMENT-FRIENDLY NONPOLARIZING ELECTRODES

In the last few years our attention has been turned to the phenomenon that the matrix of non-polarizing electrodes (gypsum+PbCl2 material filled in the body of electrode) loses mass during some time of usage, mostly in case of under water use (Figure 3). The reason for this is that the material degrades (like dissolves) from the free matrix-surface (at the bottom of electrode) and gets into the environment where the electrode is placed (watered ground, bag filled in with bentonite mud, water of reservoir, etc.). On this account the matrix loses mass at the bottom of electrode. After some time the Pb-spiral may get out of the matrix-material so the electrode becomes unusable. The duration of this time (in fact the lifetime of the electrode) depends on the mass and the hardness of matrix so may range from several weeks (for small type), up to several months or year ( for the medium, long, big types) depending on the frequency of usage in this period as well.

The degraded material of the matrix getting into the environment may cause some pollution (Pb pollution) mostly in case of use under water. Using the electrodes on the ground surface or placed into �bentonite bag� the part of contaminated ground (considerably less polluted compared to the under water case) can be easily removed.

To avoid environmental pollution and to increase the lifetime of the electrodes we have modified their structure by setting a porous ceramic plate (saturated with the same solution than the matrix) at the bottom of the matrix in full contact with it (Figure 4.).

In this way the electrical conductance has been assured between the electrode and the environment but the ceramic plate arrests the degradation of the matrix since this plate does not degrade. At the same time the life-time of electrodes will be longer.
The other features of the electrode (the content of the matrix, Pb-spiral, dimensions) has not been changed.

Laboratory analysis has been performed on usual and environment-friendly medium electrodes to investigate the leakage of some ingredient elements, anions, cations into the environment (in this case ordinary water). The analysis was performed (with accredited method and equipment JY ULTIMA 2C ICP-OES) in he laboratory of Geological Institute of Hungary for the Ca, Mg, Na, K, Fe, Mn, Cl, SO4, Pb, Zn, Cu, Ni, Al.
The electrode was placed into a container with 5 l water. Each time a sample was taken for analysis, the water was mixed in advance to ensure that some degraded material gets into it as well. 0,2 ml HNO3 concentrate was added to the sample (making up PH with value 2) for solving out the Pb and Cl components from the degraded material.

One can see in the following graphs the quantity of the materials of interest for us, (anions, cations; see above with bold characters) contained in the samples, plotted against the time.
Figure 3. : Loss of the matrix material from the bottom of medium electrode
Figure 4. : Environment-friendly (first, with porous ceramic plate at the bottom) and usual (second) medium electrode
Important note: the ground has higher (usualy 5-9) PH values than our samples (2 PH) so the solving  of the degraded matrix (and moving the Pb  component) is considerably decreased than it occured in the analysed samples.
REFERENCE LIST
The main users of our nonpolarizing electrodes

Since more then 10 years
ITALY
       
Geosystem srl
         Geoinvest srl
         Instituto di Geoscienze e Georisorse (Pisa)
GERMANY
        
Metronix Messgerate und Elektronik GmbH
      
TEXPLOR Exploration and Environmental Technology GmbH
HUNGARY
 
      E�tv�s Lorand Geophysical Institute of Hungary
         MOL Hungarian Oil and Gas Co.
PORTUGAL:
          Instituto de Ciencias da Terra e do Espaco

Since less than 10 years
GERMANY
          Bundesanstalt f�r Geowissenschaften und Rohstoffe (BGR) Geozentrum Hannover
          TERRATEC Geophyisical Services
USA
     
   Schlumberger Technology Corp. EMI Technology Center
IRELAND
    
    Dublin Institute for Advanced Studies
INDIA
       
National Geophysical Research Institute (Hyderabad)
JAPAN
          Geothermal Energy Research and Development Co. Ltd
CZEH REPUBLIC
          Geofizykaln� �stav AV CR v.v.i.

Other users
Universitat de Barcelona Dept. Geodinamica i Geofisica
BRGR (French Geological Survey)
IRIS (Oregon State University College of Oceanic and Atmospheric Sciences
EMpulse Geophysics Ltd (Canada)
ELTA-GEO Ltd (Russia, Novosibirsk)
Instituto Costarricense de Electricidad (Costa Rica)
Universita Degli Studi di Padova (Italy)
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