Incineration4 MSW Combustion
IV. Problem Solving
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Air is more than just oxygen. It is nitrogen, oxygen,
water vapor, carbon dioxide, and other trace gases.
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Air Composition
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Nitrogen - 78.08%
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Oxygen - 20.94%
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Argon - 0.93%
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Carbon Dioxide and other trace gases - 0.04%
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Water Vapor - 1 to 4 %
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The important point is that air is about 21% oxygen
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Type I Problem - calculation of air requirements and
flue gas composition
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First, determine the amount of oxygen required to combust
a known mass of waste (or fuel) into its combustion end products
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C + O2 ® CO2
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2H2 + O2 ® 2H2O
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S + O2 ® SO2 (SOx)
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N2 ® N2 (NOx also)
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Convert the amount of oxygen calculated above into the
amount of air required knowing that air is approximately 21% oxygen. This
is the 0% Excess Air (EA) condition.
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50% EA is 1.5 times the 0% EA
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100% EA is 2 times the 0% EA
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Determine the waste (or fuel) feed rate.
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Based on the values calculated in the two steps above,
calculate the air feed rate for any of the EA conditions.
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The flue gas composition is simply the combustion products
plus that portion of the feed air that is not changed (i.e. - all non-oxygen
components and oxygen in excess of that required for combustion)
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Type II Problem - calculation of flue gas temperature
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To do this problem, you need to know
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The flue gas composition
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The energy content of the incoming waste (or fuel)
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The energy conversion efficiency
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The enthalpy of the flue gases at various temperatures.
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Calculate the anticipated energy content of the flue
gas. This is the energy content of the incoming waste (or fuel) times the
energy conversion efficiency.
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Calculate the energy content of the flue gas at various
temperatures. This calculation is based on the flue gas composition and
the gas enthalpy at a specific temperature.
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By interpolation determine at what temperature the calculation
from 3 above is equal to the value calculated in 2 above.
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Type III Problem - total system analysis
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Incorporates concepts from Type I and Type II problems
as well as overall system behavior.
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Heat (energy) losses are attributed to various process,
interactions, and components of system (heating of water, radiant losses,
energy recovery, heating of ash, etc.)
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Composition of flue gas is a function of not only the
design stoichiometry and air supplied. It is also effected by the incomplete
combustion of the waste.