Chapter 6

The Chemistry of Life

Elements

n    Everything that has mass is made of substances called elements

n    Elements are the different types of atoms

n    You can’t break them down any further without changing their chemical properties

Elements in Life

n     Big 6 in Life (not necessarily humans): CHNOPS

n    Carbon, Hydrogen, Nitrogen, Oxygen,  Phosphorus, Sulfur

n     Trace elements

 

Atoms

n    An atom is the smallest particle of an element that has the characteristics of that element

n    The “basic building blocks of all matter”

n    Atom of gold to the right

Structure of at Atom

n   Nucleus – center of atom

n    Contains protons (positively charged particles)

n    And neutrons (neutrally charged particles)

n   Each element has a distinct number of protons (the atomic number)

n   Electrons are negatively charged particles that “orbit” the nucleus

n    Electron clouds

Bohr Model of Atom

n    Simplified way of showing how electrons orbit the nucleus of an atom

n    2 electrons in first shell

n    8 electrons in each subsequent shell

Isotopes

n    Isotopes are atoms of the same element that have different numbers of neutrons

n    Unstable isotopes break down to more stable ones and give off radiation

n    Useful in radioactive dating, atomic bonds, etc.

Compounds & Bonding

n    A compound is a substance that is composed of atoms of two or more different elements that are chemically combined

n    Covalent bonds form when atoms share electrons

n    Stronger bonds

 

Ionic Bonds

n    Ions are charged particles

n    They either lose or gain electrons

n    Ionic bonds are formed when ions of opposite charges are attracted to each other

Chemical Reactions

n    Chemical reactions occur when bonds are formed or broken, forming new substances

n    Metabolism refers to all of the chemical reactions that occur within an organism

 

Writing Chemical Equations

n    Reactants undergo chemical reactions and are generally written on the left

n    Products are substances formed from chemical reactions and are generally written on the right

n    An arrow indicates which way the reaction flows (can be a 2-way arrow)

Mixtures & Solutions

n    A mixture is a combination of substances in which the individual components retain their own properties

n    i.e. – stirring sand and sugar together

n    A solution is a mixture in which one or more substances (solutes) are distributed evenly in another substance (solvent)

n    i.e. – sugar dissolving in water & Kool-Aid

Acids & Bases

n   An acid is any substance that forms hydrogen ions (H+) in water

n   Has a pH below 7

n   A base is any substance that forms hydroxide ions (OH-) in water

n   Has a pH above 7

Water

n    Life occurs where water exists

n   Makes up 70-95% of most organisms

n    Water is polar

n   Polar molecules have an unequal distribution of charge

n   On atom in the covalent bond “hogs” the electrons and becomes more negative

n   The other atom becomes more positive

n    Hydrogen bonds form between water molecules

n   Weak bond between two polar molecules

Properties of Water

n    Capillary action - water an creep up thin tubes

n    Due to polarity & surface tension

n    Allows water to go up xylem in plants without using energy

n    Water resists changes in temperature

n    Helps maintain homeostasis

Properties of Water

n    Water expands when it freezes

n    Most things get more dense

n    Allows ice to float, to break up rocks into soil

Brownian Motion

n   1827, Scottish scientist Robert Brown looked at pollen grains in water under a microscope

n   He noticed that they were constantly moving

n   He was observing that all atoms and molecules randomly move

Diffusion

n   The net movement of particles from an area of higher concentration to an area of lower concentration

n   Occurs due to Brownian Motion

n   Diffusion is slow

n   Can be sped up by

n   Increased Concentration

n   Increased Temperature

n   Increased pressure

Diffusion

n   Equilibrium is met when there is continuous movement but no overall concentration change

n   Diffusion occurs into and out of cells constantly

Carbon

n     Single Bond – two atoms share one pair of electrons

n     Double Bond – two atoms share 2 pairs

n     Triple Bond – two atoms share 3 pair

n     Every organic molecule has carbon

n     Carbon is unique because it has 4 “empty spots” in it’s outer shell and can share an electron with up to 4 other atoms

 

Biomolecules

n    Biomolecules are large organic compounds

n    Polymers are large molecules formed when many smaller molecules bond together

n    The Main Ones

n    Carbohydrates

n    Lipids

n    Proteins

n    Nucleic acids

Carbohydrates

n     Biomolecule composed of carbon, hydrogen, and oxygen in a ration of about 2 hydrogen atoms and 1 oxygen atom for every carbon

n     Monosaccharide

n    Simplest carbohydrate – a simple sugar

n    Glucose & fructose

n     Disaccharide

n    Combine two monosaccharides

n    Glucose + fructose = sucrose

Carbohydrates

n   Polysaccharides

n   Polymers composed of many monosaccharides

n   Glycogen – storage form in animals

n   Starch – storage form in plants

n   Cellulose – Cell walls & structual support

 

Lipids

n     Large biomolecules that are made mostly of carbon and hydrogen with a small amount of oxygen

n     Include fats, oils, waxes and steroids

n     Fatty acids are common lipids

n    Fatty acids linked with glycerol

n    Can be saturated (all single bonds – more solid)

n    Monounsaturated (one double bond)

n    Polyunsaturated (multiple double bonds – more liquid)

Lipids

n  YOU NEED FAT!

n  Lipids store energy, insulate, provide protective coverings

n  Steroids are “messengers”

Proteins

n  A large, complex polymer composed of carbon, hydrogen, oxygen, nitrogen and sometimes sulfur

n  Provide structure for tissues and organs

n  Carry out cell metabolism

Structure of Proteins

n    Amino acids are the building blocks (monomers) of proteins

n    There are 20 common amino acids

n    Amino acids are joined by peptide bonds

n    Water is removed

n    There are many “levels” to a protein formation

n    Different turns, twists, etc in the protein can change it’s function

Proteins – Enzymes

n    Enzymes are proteins that function as a catalyst

n    Speed up the rate of a chemical reaction

n    Essential to make reactions go fast enough to keep organisms alive.

Nucleic Acids

n   Complex biomolecule that stores cellular information in the formation of a code

n   Polymers of nucleotides

n   Used to store and transfer information

Nucleic Acids

n  DNA – double stranded

n  Contains “master code” for an organism

n  RNA – single stranded

n  Carries information to help make proteins

 

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