| NASA 1966 All-Stars and Award Winners | ||
| Catcher | Tom Haller | Iowa |
| 1st Base | Willie McCovey | Sacramento |
| 2nd Base | Jim Lefebvre | Sacramento |
| 3rd Base | Dick Allen | Iowa |
| Shortstop | Bert Campaneris | Mercury |
| Outfield | Willie Mays | Boise |
| Outfield | Lou Brock | Mercury |
| Outfield | Lou Johnson | Bedford |
| RHSP | Bob Gibson | Iowa |
| LHSP | Mike Cuellar | Sacramento |
| Reliever | Jack Aker | Bedford |
| MVP | Willie Mays | Boise |
| Cy Young | Bob Gibson | Iowa |
| Rookie of the Year | Lou Johnson | Bedford |