Chapter 14-15

 

Multiple Choice

Identify the letter of the choice that best completes the statement or answers the question.

 

____          1.      One physical property of acids is a _____.

a.

slippery feel

c.

sour taste

b.

pink color

d.

presence of hydrogen

 

 

____          2.      Acids react with carbonates to produce _____.

a.

hydrogen

c.

a hydronium ion

b.

a base

d.

carbon dioxide

 

 

____          3.      The top industrial chemical produced in the United States for many years has been _____.

a.

sulfuric acid

c.

hydrochloric acid

b.

ammonia

d.

oxygen

 

 

____          4.      An example of a polyprotic acid is _____.

a.

HCl

c.

H2SO4

b.

HC2H3O2

d.

HCN

 

 

____          5.      A piece of blue litmus paper placed into water through which carbon dioxide gas is bubbled will _____.

a.

turn pink

c.

show no change

b.

remain blue

d.

lose its color

 

 

____          6.      The weak acid in the following list is _____.

a.

hydrochloric acid

c.

nitric acid

b.

sulfuric acid

d.

acetic acid

 

 

____          7.      Conductivity of an acid or a base in water is affected by all of the following except _____.

a.

strength

c.

molarity

b.

an indicator

d.

pH

 

 

____          8.      The type of acid-base reaction that always goes to completion is the reaction between _____.

a.

a weak acid and a weak base

c.

a strong acid and a weak base

b.

a weak acid and a strong base

d.

a strong acid and a strong base

 

 

____          9.      The spectator ions in the reaction between HNO3 and NH4OH are _____.

a.

NH4+ + NO3-

c.

NH4+ + OH-

b.

H+ + OH-

d.

H+ + NO3-

 

 

____          10.      According to the Bronsted-Lowry definition, an acid is a substance that _____.

a.

releases H+ in solution

c.

accepts protons

b.

donates hydrogen atoms

d.

donates protons

 

 

Completion

Complete each sentence or statement.

 

                  11.      The combination of a water molecule and a hydrogen ion is a(n) ____________________.

 

                  12.      A(n) _______________ is a substance that produces hydroxide ions in water.

 

                  13.      The reaction between an acid and a base is a(n) _______________________.

 

Consider this equation for the following questions:

K+(aq) + OH-(aq) + H+(aq) + Br-(aq) ® H2O(l) + K+(aq) + Br-(aq).

 

                  14.      You can tell from the equation that certain ions do not actually take part in the reaction. These ions are called __________________.

 

                  15.      In order to conduct a titration reaction, you would have to begin with a(n) ______________________ of either the acid or base.

 

Matching

 

Match each of the following equations with the letter that tells what the pH of the final solutions that form would be.

a.

low (about 1-2)

d.

moderately high (about 8-9)

b.

moderately low (about 5-6)

e.

high (about 13-14)

c.

neutral (7)

 

 

 

____          16.      NaOH + HCl ®

 

____          17.      H2O ®

 

____          18.      NH3 + H2O ®

 

____          19.      H2O + CO2 ®

 

____          20.      HCl + H2O ®

 

Short Answer

 

                  21.      How does the concentration of hydrogen ions in a solution with a pH of 3 differ from a solution with a pH of 6?

 

                  22.      Give the formula for sodium hydroxide, and identify it as a strong base or a weak base.

 

                  23.      Classify each of the following as an acid, a base, or neither when mixed with water: SO2, HC6H5CO2, CsOH, and C3H8.

 

                  24.      Use a chemical equation to show how aqueous carbonic acid fits the definition of an acid.

 

                  25.      Write equations that show what will happen when a hydrogen ion or hydroxide ion is added to the following buffer solution:

lactic acid (HC3H5O3) and sodium lactate.

 

                  26.      Identify the spectator ions in the following reaction:

sulfuric acid, H2SO4, and aluminum hydroxide, Al(OH)3

 

                  27.      A 0.800M NaOH solution was used to titrate an HCl solution of unknown concentration. At the endpoint, 17.2 mL of NaOH solution had neutralized 50.0 mL of HCl. What is the molarity of the HCl solution?

 

                  28.      An NaOH solution of unknown concentration was used to titrate 20.0 mL of a 0.200M solution of oxalic acid, H2C2O4. If 48.1 mL of NaOH are used to reach the endpoint, what is the concentration of the NaOH solution?

 

                  29.      How many milliliters of 0.110M Ca(OH)2 are needed to neutralize 30.0 mL of 0.500M HNO3?

 

                  30.      What volume of 0.100M HClO4 is needed to neutralize 75.0 mL of 5.00M KOH?

 

Problem

 

This table summarizes some properties of eight compounds. Complete the table by supplying the correct information in the spaces provided.

 

 

Compound

Degree of ionization

Acid or

base

Strong or

weak

Ionization equation

HC2O3O2

2%

acid

weak

HC2H3O2 + H2O ® H3O+ + C2H3O2-

RbOH

100%

a.

b.

c.

HCN

d.

acid

e.

f.

H2O

10-5%

both

g.

h.

H3PO4

i.

j.

k.

l.

m.

0.01%

n.

o.

CH3NH2 + H2O ® CH3NH3+ + OH-

KNO3

p.

q.

r.

s.

HFO4

t.

u.

strong

v.

 

 

                  31.      b. _______________

 

                  32.      i. _______________

 

                  33.      l. _______________

 

                  34.      r. _______________

 

                  35.      u. _______________

 

Each of the following salts is dissolved in water. Predict whether the solution formed would be acidic, basic, or neutral.

 

                  36.      K2CO3

 

The table shows the data collected in a series of five titration experiments between samples of nitric acid and sodium hydroxide. From the information in the table, determine the missing values.

 

Experiment

Acid

Base

 

molarity

volume

molarity

volume

101

0.10M

40.0 mL

0.20M

a. ______

102

b. ______

50.0 mL

0.14M

70.0 mL

103

0.40M

30.0 mL

c. ______

25.0 mL

104

0.010M

d. ______

0.0077M

65.0 mL

105

2.0M

16.0 mL

e. ______

25.0 mL

 

 

                  37.      a. _______________

 

                  38.      d. _______________

 

                  39.      An amphoteric substance may act as either an acid or a base. The dihydrogen phosphite ion is amphoteric. Write reactions that demonstrate this property of H2PO3¯.

 

                  40.      Write an overall equation for the acid-base reaction that would be required to produce the following salt: Mg(ClO4)2.

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