Limed hides and skins are called "PELTS" and at this stage are free from
hair and plump. The excess flesh from the flesh side is removed on fleshing
machines or by hands.
The alkaline chemicals used in the liming process are
still present in relatively large amounts in two forms. a)partly as free alkali
and b)partly as chemically combined with collagen. Now that their utility is served,
they should be removed. Free alkali which is soluble in water is removed partially
bywashing the pelts in water. After washing, chemically combined alkali is removed
by neutralising it with acids, acid salts, ammonium slats or substances with acidic
reaction.
A number of chemicals are available for this prupose. The most
commonly used are:
- Acids:
- Hydrochloric acid
- Sulphuric Acid
- Formic Acid
- Acetic Acid
- Lactic Acid
- Boric Acid
- Naphthalene sulphonic acid
- Acid salts:
- Sodium bisulphate
- Sodium bisulphate
- Ammonium Salts:
- Ammonium Chloride
- Ammonium Sulphate
Strong acids like hydrochloric and sulphuric rarely used.
They are applied, if at all, in a vert diluted form. In a concentrated form they swell the
grain and produce cracky leather. While using these deliming agents the amount applied
should be such that the pH of deliming bath does not fall below 5, since acid swelling
can occur which produces coarse and cracky grain. Among the acids, formic and lactic acids
are generally used for deliming as they are very weak and do not swell the grain of the pelt
to any appreciable extent.
Ammonium sulphate and ammonium chloride are most
regularly used as deliming agents. Of these two, ammonium sulphate is considered to
be better, since in neutralising lime, calcium sulphate formed gives some filling
action. When ammonium chloride is used, calcium chloride is formed which has some
solvent action on hide protein, making the leather poorer in substance and inferor in
quality.