Standard Steels  

According to the chemical compositions, standard steels can be classified into three major groups: 

Carbon Steels, Alloy Steels, Stainless Steels
Steels Compositions
Carbon Steels Alloying elements do not exceed these limits: 1% carbon, 0.6% copper, 1.65% manganese, 0.4% phosphorus, 0.6% silicon, and 0.05% sulfur.
Alloy Steels Steels that exceed the element limits for carbon steels. Also includes steels that contain elements not found in carbon steels such as nickel, chromium (up to 3.99%), cobalt, etc.
Stainless Steels Contains at least 10% chromium, with or without other elements. Based on the structures, stainless steels can be grouped into three grades:
Austenitic: Typically contains 18% chromium and 8% nickel and is widely known as 18-8. Nonmagnetic in annealed condition, this grade can only be hardened by cold working.
Ferritic: Contains very little nickel and either 17% chromium or 12% chromium with other elements such as aluminum or titanium. Always magnetic, this grade can be hardened only by cold working.
Martensitic: Typically contains 12% chromium and no nickel. This grade is magnetic and can be hardened by heat treatment.
Carbon steels are steels whose alloying elements do not exceed the following limits: 
C   max.1% Cu  max.0.6% Mn  max.1.65%
P  max. 0.4% Si  max.0.6% S   max.0.05%
Designation
Carbon steels are designated by distinct AISI (American Iron and Steel Institute) four-digit numbers. The first two digits indicate the grades of the steels, while the last two digits give the nominal carbon content of the alloy in hundredths of a percent. Here is an example:
  XX :0.xx% average carbon content
 
AISI  10 60  
   
10 >Nonresulfurized  grades
11 >Resulfurized grades
12 >Resulfurized and rephosphorized grades
15 >Nonsulfurized gradesMn content > 1%

If a letter L or B shows up between the second and third digits of an AISI number, it means that this grade is either a Leaded steel or a Boron steel; Sometimes a suffix H is attached to a AISI number to indicate that the steel has been produced to prescribed hardenability limits. Examples are:

Leaded steels :AISI 12L14, AISI 12L15...
Boron steels :AISI 15B48H...
H-steels :AISI 1038H, AISI 15B48H...
Alloy steels

 comprise a wide variety of steels which have compositions that exceed the limitations of C, Mn, Ni, Mo, Cr, Va, Si, and B which have been set for carbon steels. However, steels containing more than 3.99% chromium are classified differently as stainless  and tool steels.Alloy steels are generally more responsive to heat and mechanical treatments than carbon steels. 

AISI Designation
Typically, alloy steels are designated by distinct AISI (American Iron and Steel Institute) four-digit numbers. The first two digits indicate the leading alloying elements, while the last two digits give the nominal carbon content of the alloy in hundredths of a percent. Occasionally we see five-digit designations where the last three digits tell that the carbon is actually over 1%. Here is an example:
  XXX :x.xx% average carbon content
51 100
   
13 xx:1.75Mn Manganese
23 xx:3.50Ni Nickel
31 xx:1.25Ni, 0.65-0.80Cr Nickel-Chromium
40 xx:0.20-0.25Mo Molybdenum
44 xx:0.40-0.52Mo
41 xx:0.50-0.95Cr, 0.12-0.30Mo Chromium-Molybdenum
46 xx:0.85-1.82Ni, 0.20-0.25Mo Nickel-Molybdenum
48 xx:3.5Ni, 0.25Mo
50 xx:0.27-0.65Cr Chromium
51 xx:0.80-1.05Cr
50 xxx:0.50Cr, 1.00C
51 xxx:1.02Cr, 1.00C
52 xxx:1.45Cr, 1.00C
61 xx:0.60-0.95Cr, 0.10-0.15V Chromium-Vanadium
92 xx:1.4-2Si, 0.65-0.85Mn, <0.65Cr Silicon-Manganese
43 xx:1.82Ni, 0.50-0.80Cr, 0.25Mo Nickel-Chromium-Molybdenum
47 xx:1.05Ni, 0.45Cr, 0.20-0.35Mo
81 xx:0.30Ni, 0.40Cr, 0.12Mo
86 xx:0.55Ni, 0.50Cr, 0.25Mo
87 xx:0.55Ni, 0.50Cr, 0.25Mo
88 xx:0.55Ni, 0.50Cr, 0.20-0.35Mo
93 xx:3.25Ni, 1.20Cr, 0.12Mo
94 xx:0.45Ni, 0.40Cr, 0.12Mo

If a B shows up between the second and third digits of an AISI number, it means that this grade is a Boron steel; Sometimes a suffix H is attached to a AISI number to indicate that the steel has been produced to prescribed hardenability limits.

 

Stainless steels 
Stainless steels are high-alloy steels that have superior corrosion resistance than other steels because they contain large amounts of chromium. Stainless steels can contain anywhere from 4-30 percent chromium, however most contain around 10 percent. Stainless steels can be divided into three basic groups based on their crystalline structure: austenitic, ferritic, and martensitic. Another group of stainless steels known as precipitation-hardened steels are a combination of austenitic and martensitic steels. Below are the general compositional contents of these groups.
Grades
Ferritic grades: Ferritic stainless steels are magnetic non heat-treatable steels that contain chromium but not nickel. They have good heat and corrosion resistance, in particular sea water, and good resistance to stress-corrosion cracking. Their mechanical properties are not as strong as the austenitic grades, however they have better decorative appeal.

Martensitic grades: Martensitic grades are magnetic and can be heat-treated by quenching or tempering. They contain chromium but usually contain no nickel, except for 2 grades. Martensitic steels are not as corrosive resistant as austenitic or ferritic grades, but their hardness levels are among the highest of the all the stainless steels.

Austenitic grades: Austenitic stainless steels are non-magnetic non heat-treatable steels that are usually annealed and cold worked. Some austenitic steels tend to become slightly magnetic after cold working. Austenitic steels have excellent corrosion and heat resistance with good mechanical properties over a wide range of temperatures. There are two subclasses of austenitic stainless steels: chromium-nickel and chromium-manganese-low nickel steels. Chromium-nickel steels are the most general widely used steels and are also known as 18-8(Cr-Ni) steels. The chromium nickel ratio can be modified to improve formability; carbon content can be reduced to improve intergranular corrosion resistance. Molybdenum can be added to improve corrosion resistance; additionally the Cr-Ni content can be increased.

ANSI  2XX Stainless steel  

Name Alloy Type
ANSI 201, 202, 205 Austenitic standard
Chromium-Manganese-Nickel steel 
ANSI 216  Austenitic nonstandard
Chromium-Manganese-Nickel steel 

ANSI 3XX

Name Alloy Type
ANSI 301, 302, 302B,302Cu, 303, 303SE, 304, 304H, 304L, 304LN, 304N, 305, 308, 309, 309S, 310, 310S, 314, 316, 316F, 316H,316L, 316LN, 316N Austenitic standard
Chromium-Nickel steel 
ANSI 303PlusX, 304HN, 308L, 309Cb+Ta, 309SCb, 312 Austenitic nonstandard
Chromium-Nickel steel 

ANSI 4XX 

Name Alloy Type
ANSI 403, 410, 414, 416, 416Se, 418, 420, 420F, 422, 431, 440A, 440B, 440C Martensitic standard
Chromium steel 
ANSI 410Cb, 410S, 414L, 416PlusX Martensitic nonstandard
Chromium steel 
ANSI 405, 409, 429, 430, 430F,430FSe, 434, 436, 442, 446 Ferritic standard
Chromium steel 
ANSI 404, 430Ti, 444  Ferritic nonstandard
Chromium steel 

 

Tool Steels  

 

 typically have excess carbides (carbon alloys) which make them hard and wear-resistant. Most tool steels are used in a heat-treated state, generally hardened and tempered.

Rod and Plate Tool Steels

AISI SAE 0-1
This is an electric furnace melt oil hardening tool steel. A non-shrinking general purpose tool steel, it has excellent abrasion resistance, toughness and machinability characteristics.
Analysis C .85-1.00, Mn 1.00-1.40, Si .50, Max, Cr. .40-.60, W.40-.60 Max.

AISI SAE A-2
Fine grain, electric furnace air hardening, 5% chrome tool steel.  It is a superior quality steel which has excellent wear and abrasion resistance properties.
Cold-Work , Medium-Alloy, Air-Hardening.
Analysis C.95-1.25, Mn 1.00 Max, Cr 4.75-5.50, Mo .90-1.4, V.15-.50

AISI SAE W-1
W-1 water hardening is the most popular, versatile, and least expensive grade of tool steel. Its high carbon content allows it to be used often without heat treatment for maintenance applications. It is a fine grained electric furnace melted commercial grade tool steel which is supplied in the fully spheroidized 100% decarb free condition.
Analysis C .95-1.05, Mn .30-.40, Si .10-.25

AISI SAE S-7
S-7 Hi-shock tool steel is an excellent chock steel that can be and is often used in hot work applications where the tool temperature does not exceed 1000 deg. F.  This tool steel combines the qualities of high strength and good ductility for cold and medium hot work application.
Analysis C .45-.55, Mn .20-.80, Si .20-1.00, Cr 3.0-3.5, V .20-.30, Mo 1.30-1.80

AISI SAE D-2
Fine quality, air hardened, electric furnace melt tool steel. The combination of superior abrasion resistance and toughness found in D-2 results from its high carbon and high chromium composition. High chrome is an extraordinary tool steel that can be specified for the most demanding applications. This is  non-free machining tool steel.
Cold-Work ,High-Carbon, High-Chromium.
Analysis C 1.40-1.60, Mn .60 Max, Cr 11.00-13.00, V 1.10 Max, Mo .70-1.20, Co 100 Max

AISI SAE L
Low-Alloy tool steel

AISI SAE F
Carbon-Tungsten

AISI SAE P1 - P19                             P20 - P39
Low-Carbon Mold Steels             Other Mold Steels

AISI SAE H1 - H19                             H20 - H39                                   H40 - H59
Chromium-Base Hot Work       Tungsten-Base Hot Work    Molybdenum-Base Hot Work

 AISI SAE T
High - Speed   (Tungsten - Base)

 AISI SAE M
High - Speed   (Molybdenum - Base)