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Gold Extraction Using Cyanide Leaching

Chris Van de Ven

High gold prices since the early 1980s have resulted in a dramatic rise in gold production. The most common method of gold extraction for large scale mines is also an environmentally dangerous method. Modern gold mining produces large volumes of toxic solids and liquids. With modern techniques, microscopic pieces of gold can be extracted from ore rocks, making unprofitable mines profitable. This mining method is called cyanide leaching.
Cyanide leaching, uses a cyanide solution to dissolve gold from host rocks for later precipitation. Rock is removed from the ground with explosives. After the ore has been excavated, it is brought to a grinding mill, where the ore is crushed into sand or smaller sized grains. Next, it is transported to the leaching plant where the ore is mixed with the cyanide solution. The cyanide solution dissolves the gold from the crushed ore. Next, the gold-bearing solution is collected. Finally, the gold is precipitated out of solution.

One method of precipitation is to add a different metal to the solution. The added metal dissolves and causes the gold to precipitate out of solution. The precipitate is collected and impurities are removed in a refinery. Another method of removing the gold from solution is to add a metal cathode. When an electrical current is applied, the positively charged gold precipitates onto the negatively charged metal cathode. In a refinery, the gold is melted off the metal cathode and impurities are removed from the melt. The remaining molten gold is poured into a mold and cooled [Ripley, Redmann, and Crowder, 1996].

Cyanide leaching produces many hazardous waste products that must be disposed of properly. Some of these hazardous materials are acids and heavy metals, but the most hazardous compounds are the cyanide compounds. The cyanide compounds are extremely toxic to most animals and can destroy an ecosystem if significant amounts of the solutions escape. If the solutions get into soils, plants absorb the cyanide-bearing solutions [Noble and Howe, 1980]. Cyanide accumulates in the plants and often proves deadly for grazing livestock.
Only with careful handling of wastes are these hazards kept from the environment. The Homestake Mine in Lead, South Dakota, is an example of a mine using cyanide leaching techniques that operates without having a negative environmental impact. The Homestake Mine produces about twelve tons of gold each year [Bachman and Caddy, 1990]. Large amounts of gold also result in large amounts of hazardous waste. At the mine, the Grizzly Gulch tailings dam is used to settle out hazardous solids and offers a large reservoir for hazardous liquids to degrade naturally. To prevent water from infiltrating the reservoir and creating more contaminated water, a trench was dug around the mine to capture surface runoff. Another trench was dug downstream to capture ground water flowing from under the reservoir. These trenches act as safety measures that isolate hazardous materials from the surrounding environment. In an effort to further reduce the amount of contaminated liquids, Homestake Mine uses water from the tailings dam in gold extraction processes. Recycling reduces the amount of fresh water that becomes contaminated by mine wastes.
Homestake Mine has shown that with careful planning and safety measures, a cyanide leaching operation does not have to contaminate the surrounding ecosystems.

References

Bachman, R. L., and S. W. Caddey, "The Homestake Mine, Lead, South Dakota: An Overview," Metallogeny of Gold in the Black Hills, South Dakota: A Guidebook Prepared for the Society of Economic Geologists Field Conference, September 5-9, 1990, Colin J. Paterson and Alvis L. Lisenbee, eds. (Fort Collins, Colorado: The Society of Economic Geologists, 1990).
Noble, Daniel L., and Sr. Marmion Howe, "Cyanide in Riparian Vegetation," Gold, Silver, Uranium, and Coal: Geology, Mining, Extraction, and Environment, M. C. Fuerstenau and B. R. Palmer, eds. (New York: The American Institute of Mining, Metallurgical, and Petroleum Engineers, 1983).
Ripley, Earle A., Robert E. Redmann, and Adele A. Crowder, Environmental Effects of Mining (Delray Beach, Florida: St. Lucie Press, 1996).

Author's Note: Chris Van de Ven graduated with a bachelors degree in Geological Engineering from the University of Wisconsin-Madison. He is now a graduate student at Stanford University. (Back to Beginning)

From:

http://elvis.engr.wisc.edu/690S99/mschroep/project/uer97/author4/index.html

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