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One method of precipitation is to add a different metal to the solution. The added metal dissolves and causes the gold to precipitate out of solution. The precipitate is collected and impurities are removed in a refinery. Another method of removing the gold from solution is to add a metal cathode. When an electrical current is applied, the positively charged gold precipitates onto the negatively charged metal cathode. In a refinery, the gold is melted off the metal cathode and impurities are removed from the melt. The remaining molten gold is poured into a mold and cooled [Ripley, Redmann, and Crowder, 1996].
From:
http://elvis.engr.wisc.edu/690S99/mschroep/project/uer97/author4/index.html