thermodynamic (Kelvin) scale of temperature: Symbol K. The efficiency of Carnot engine* is equal to,

e = (Q1 - Q2) / Q1 = 1 - Q2/Q1

where Q1 is the heat extracted from the reservoir and Q2 is the heat rejected at the sink, by the engine. The ratio of Q1 and Q2 depends only on the temperature of the reservoir and the sink and nothing else. It was proposed by Lord Kelvin that if this fact is used in defining a temperature scale then it would be independent of the properties of any particular substance. The Kelvin temperature of the reservoir (T1) and the sink (T2) between which Carnot engine operates are defined by the relation,

Q1 / Q2 = T1 / T2

Further the scale is fixed by assigning arbitrarily the temperature of triple point* of water as 273.16 K, which is 0.01oC in the Celsius scale. Therefore if T is the temperature in the Kelvin scale, the corresponding temperature in the Celsius scale is,

toC = T K - 273.15

The temperature 0 K or -273.15oC is called `absolute zero', since this temperature is the lowest temperature theoretically possible.

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