heat capacity SI unit J.K-1 If a quantity of heat D Q produces a change of temperature D T in a body, then heat capacity is defined as
heat capacity = D Q/ D T [J/K]
The quantity of heat D Q required to produce a change in temperature D T is proportional to the mass of the sample, m and difference in temperature D T.
D
Q = cm D T (h4)where c is a constant for a particular substance called the specific heat. The SI unit of specific heat is J.kg-1.K-1. Sometimes it is preferable to use molar specific heat which is the heat capacity per mole of a substance. In table HI the specific heat of some important materials are listed.
Table HI Specific heat at 20° C and 1 Atm.
|
|
c ( J.kg-1.K-1) |
|
aluminium |
900 |
|
copper |
385 |
|
steel/iron |
450 |
|
lead |
130 |
|
water |
4190 |
|
ice |
2100 |
|
steam(100°C) |
1950 |
|
concrete(18°C) |
837 |
Specific heat varies with temperature. When a substance transforms from one state to another, there is an abrupt change in the specific heat.
Temperature of a gas can be raised by two ways. First by keeping its volume constant, and second by keeping its pressure constant. Therefore for a gas we have to define two specific heats; specific heat at constant volume Cv and specific heat at constant pressure Cp. The two specific heats per mole of an ideal gas are related as,
Cp = Cv + R
where R is universal gas constant. For a solid or liquid the volume change is small, and in practice Cp is usually measured.