About 4-Digit ID numbers for PetroChemicals The US Department of Transportation in conjunction with a growing number of other nations has constructed and published an Emergency Response Guidebook, which gives a pre-staged set of emergency procedures for first resonders (fire, law enforcement) to follow upon managing a hazardous material incident. Such incidents can involve: 1. Found material that is not controlled 2. Spilled material 3. Exposure of material to people and / or animals 4. Contamination of soil, roads, drainage or other waterways and reservoirs 5. Risk of any kind to life and safety. Because petrochemicals are transported daily via different means, it became necessary to support the differing transportation methods with one standard system of placarding, or labeling, hazardous materials that include petrochemicals. Some means of transporting petrochemicals include: 1. trucks 2. railcar 3. pipeline 4. barge and other motor vessels on water 5. ULCC, VLCC, oil tankers 6. aircraft 000.