FreeLearning
This is completely free, including membership. They also have chat/forum so you can practice what you've learned.
http://www.englishpage.com
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Sign up for a free membership and receive a free monthly lesson sent directly to your email. They aslo offer affordable learning materials.
http://www.english-to-go.com
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This one looks pretty good so far.
Let me know what you think?
I like the Hangman game.
http://www.eslus.com/eslcenter.htm
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Test your English here.
http://www.free-toeic.com
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Learn Spanish for Free. They offer a free Spanish CD-ROM, Vocabulary & Newsletter. You can also purchase coarses here.
http://www.learnspanishtoday.com
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They offer a free Spanish lesson every month. Just click on the link (Free Spanish lesson) on the left side of the screen.
http://www.elemadrid.com
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They also have an archive of previous lessons.
http://www.spanishunlimited.com
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For their free sample lessons you'll need to have Macromedia Flash Player. Don't worry if you don't have it, you can download from there for free. That's right free. I just love free.
http://www.spanishprograms.com
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A free online tutorial. http://www.studyspanish.com
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Register for free and start learning French. This is an interactive site, which I think makes learning more enjoyable. Give it a try.
http://www.frenchassistant.com/default.asp
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Jacques' Leon is your instructor of Basic French. This is very well organized. It covers pronunciation, sentence structure and much more. No registration is required.
http://www.jump-gate.com/languages/french
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http://academic.brooklyn.cuny.edu
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http://cyberitalian.com
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Learn PERSIAN (FARSI)
http://www.easypersian.com
Such as: Arabic, Cherokee, Chinese, Dutch, English, Finnish, Greek, German, Hindi, Indonesian, Italian, Japanese, Korean, Kurdish, Lao, Latin, Maltese, Norwegian, Polish, Quechua, Russian, Serbian, Swahili, Thai, Turkish, Ukrainian, Vietnamese, Welsh, Xhosa and many more...
http://www.word2word.com/course.html
http://www.people.fus.harvard.edu
French, Spanish, German, Italian, English & Portugese.
http://www.yourdictionary.com