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Other aliases: NeoDude, Return of Neo
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Jim
Type: Preexisting
Jim is the groundskeeper of Kadic College. His general responsibilities include security, enforcement of rules, and overseeing detentions, among other things. He's got a soft heart, however, and will always stop to help someone in need.
Late in Chapter 7. Jeremie tells Jim the story on Lyoko, and he decides to help them out. He can't be virtualized, but he's still a powerful ally.