NANOTHERMIONIC
UPDATED DECEMBER 10, 2005
Sang H. Choi of Langley Research Center
Thermo-electron ballistic (TEB) coolers or heaters
The combination of ballistic motion and large current density should make it possible for
TEB devices to operate at low applied potentials while pumping heat at rates several orders
of magnitude greater than those of thermoelectric devices. It may also enable them to operate
with efficiency close to the Carnot limit.
Electronic heat-transfer devices of a proposed type would exploit some of the quantum-wire-like,
pseudo-superconducting properties of single-wall carbon nanotubes.
RB Link
Direct link
Boeing
Solid State Thermal Engine
United States Patent Application 20040195934 Tanielian, Minas H. October 7, 2004
Abstract
The present invention is a solid state thermal engine and method for creating a solid state
thermal engine that provides an effective thermal tunneling gap between a hot and cold electrode.
The effective gap produced in the present invention is on the order of one nanometer. A via is etched
through a first side of first and second substrates, and metal electrodes are attached to a second side
of the first and second substrates. The second sides are opposite the first sides. The metal electrodes
are mated by bonding the second side of the first substrate to the second side of the second substrate.
RB Message Board Link
USPTO Link
Tanielian Group - Phantom Works - Boeing
Borealis priority date is earlier than Tanielian's - subject matter is basically the same
BACKGROUND
Novel Thermophotovoltaic Device for Direct Heat to Electricity Conversion
Status, Plans, Connections to NASA's Mission and Vision and to the Space Architect's Capability Requirements
Link
Nanalyze postings on thermionic - heat to electric - conversion.
Link

Tuominen, University of Massachusetts at Amherst, US Patent 20020158342 Oct. 31, 2002

FIG. 9 is a diagram of a single-stage thermoelectric cooler which can be made according to the methods
described herein. The substrate has electrodes pre-patterned in or on its surface. A patterned diblock copolymer
layer is created on the substrate, as described herein. Again, the matrix component of the copolymer is deleted
in FIG. 9 for clarity. Nanowires of two types are deposited by programmed electrodeposition. In the depicted
example, "n-type" nanowires, made from "n-type" materials, well known in the art, are deposited at one electrode,
and "p-type" nanowires, made from "p-type" materials, also well known in the art, are deposited at another electrode.
A top-layer metal interconnect is then deposited electrochemically. The device operates through the application of
current through the device, so that the top plate becomes cold and the electrodes and substrate become warm. The
top plate can be used as a heat sink for use in electronic devices, for example. Multistage coolers can also be made
by this fabrication method. Heating devices are also made possible by the simple adaptation of the device for such purposes.
Link to US patent filing
NALIN KUMAR, United States Patent Application 20050016575 (LIKELY PENN STATE)
January 27, 2005, Priority Date June 13, 2003
Field emission based thermoelectric device
What we claim as our invention is:
1. A device comprising an assembly containing a thermoelectric device and one or more other devices
where these other devices act as electrically conducting but thermally insulating elements.
2. A device of claim 1, where the electrically conducting but thermally insulating elements are field emission devices.

The tips can be made from either metals such as molybdenum, tungsten, nickel and copper, from semiconductors
such as silicon, gallium arsenide and gemanium, or from other materials such as graphite, diamond,
carbon nanotubes,
or from a combination thereof.

[0044] When silicon tips are used, it is possible to obtain large emitted electron current density from these tips at
an electric field of 0.5 MV/m (megavolts per meter). Using a device gap of 100 nm and a modest emitted current
density of 1 ampere per square cm, we obtain a cooling capacity of almost 1 watt per square cm. Since the applied
voltage is only 0.05 volts, the efficiency is almost 95% of the Carnot efficiency. This is much higher than 5-10%
for prior art thermoelectric coolers and 40-50% for the mechanical coolers.

Link to US 20050016575
Link to RB message 1
Link to RB message 2 re Penn State involvement
NANOCOOLING LINK
Nanomaterials draw electricity from heat
Tammy Humphrey, University of Wollongong in Australia
Heiner Linke, University of Oregon
ZT=10
Under these conditions, the thermoelectric device can operate reversibly, which means that it
attains the maximum possible efficiency � the Carnot limit (provided that heat leaks due to
phonons can be suppressed). Humphrey and Linke calculate that this energy-specific equilibrium
could produce a ZT of around 10 at room temperature: a phenomenal enhancement relative to
current bulk thermoelectrics. Given that it should not be difficult to make nanostructured materials
of this sort � for example,
from arrays of quantum dots � we might hope to see the proposal put to
the test in the near future.
Link to Nature article
Link to Nature article via RB message
Link to Physical Review Letters Abstract
Link to Physical Review Letters Paper
Link to Tammy Humprey web site
Thermoelectric Cobaltate Thin Films on Silicon
Brookhaven National Laboratory
Qiang Li
Ca3Co4O9 film can be formed on top of an amorphous silicon-oxide layer.
Link
Cooling of bulk material by electron-tunneling refrigerators
A. M. Clark and N. A. Miller
National Institute of Standards and Technology (NIST)
A. Williams and S. T. Ruggiero
University of Notre Dame
G. C. Hilton, L. R. Vale, J. A. Beall, K. D. Irwin, and J. N. Ullom
National Institute of Standards and Technology (NIST)
The work is featured in the April 25, 2005, issue of Applied Physics Letters. The NIST-designed
refrigerators, each 25 by 15 micrometers, are sandwiches of a normal metal, an insulator and a
superconducting metal. When a voltage is applied across the sandwich, the hottest electrons "tunnel"
from the normal metal through the insulator to the superconductor. The temperature in the normal
metal drops dramatically and drains electronic and vibrational energy from the objects being cooled.
Link to article
Link to Applied Physics Letters
Hosted by www.Geocities.ws

1