Hess's Law

 

 1) Zinc can be processed from its ore according to the following reaction.

2ZnS(s) + 3O2(g) + 2C(s) 2Zn(s) + 2CO(g) + 2SO2(g)

Using the data given, calculate the change in enthalpy.

2ZnO(s) + 2SO2(g) 2ZnS(s) + 3O2(g)       Δ H = 1084.24 kJ

ZnO(s) + C(s) Zn(s) + CO(g)                 Δ H = 237.76 kJ

     (a) 1322.0 kJ

     (b) -608.7 kJ

     (c) 1559.8 kJ

     (d) -846.5 kJ

 

 2) Graphite can be converted to ethane according to the following reaction.

2C(graphite) + 3H2(g) C2H6(g)

Using the data given, calculate the change in enthalpy.

C(graphite) + O2(g) CO2(g)                      Δ H = -393.5 kJ

2H2(g) + O2(g) 2H2O(l)                           Δ H = -571.6 kJ

2C2H6(g) + 7O2(g) 4CO2(g) + 6H2O(l)       Δ H = -3119.6 kJ

     (a) -84.6 kJ

     (b) -3204.2 kJ

     (c) -4084.7 kJ

     (d) 2154.5 kJ

     

 3) Sulfuric acid can be produced according to the following reaction.

2S(s) + 3O2(g) + 2H2O(l) 2H2SO4(l)

Using the data given, calculate the change in enthalpy.

   S(s) + O2(g) SO2(g)                      Δ H = -296.83 kJ

2SO3(g) O2(g) + 2SO2(g)               Δ H = -198.2 kJ

 SO3(g) + H2O(l) H2SO4(l)               Δ H = –227.72 kJ

     (a) -849.9 kJ

     (b) -722.8 kJ

     (c) -1246.3 kJ

     (d) -326.4 kJ

 

 4) Graphite can be converted to acetylene according to the following reaction.

2C(graphite) + H2(g) C2H2(g)

Using the data given, calculate the change in enthalpy.

C(graphite) + O2(g) CO2(g)                       Δ H = -393.5 kJ

2H2(g) + O2(g) 2H2O(l)                            Δ H = -571.6 kJ

2C2H2(g) + 5O2(g) 4CO2(g) + 2H2O(l)        Δ H = -2598.8 kJ

     (a) 226.6 kJ

     (b) 1633.7 kJ

     (c) -2372.2 kJ

     (d) -3563.9 kJ

 

  5) Iron can be reduced to the pure metal from the ore according to the following reaction.

Fe2O3(s) + 3CO(g) 2Fe(s) + 3CO2(g)

Using the data given, calculate the change in enthalpy.

3Fe2O3(s) + CO(g) 2Fe3O4(s) + CO2(g)     Δ H = -46.4 kJ

Fe(s) + CO2(g) FeO(s) + CO(g)                Δ H = -9.0 kJ

Fe3O4(s) + CO(g) 3FeO(s) + CO2(g)          Δ H = -41.0 kJ

     (a) -96.4 kJ

     (b) -78.4 kJ

     (c) -42.8 kJ

     (d) -24.8 kJ

 

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