Season 1
Listed By Production Number and Episode Title, Not Necessarily the Order in Which they were Aired
101 - Cartman Gets an Anal Probe
Butters is seen first here, in the back ground of class.
Pilots
1995 - The Spirit of Christmas (Jesus Vs. Santa)
102 - Weight Gain 4000
Again seen in class and punches girl in face
1992 - The Spirit of Christmas (Jesus Vs. Frosty)
103 - Volcano
No Butters in this episode
Other
104 - Big Gay Al's Big Gay Boat Ride
Butters appears in the background / crowd at the football game.
Jay Leno Comes to South Park

Has no production number as this was a 2 min short featured on The Tonight Show.
105 - An Elephant Makes Love to a Pig
Butters is in class background.
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106 - Death
Butters is in class background.
107 - Pink Eye
In background as Chubocker.
108 - Damien
You see Butters flying past in the canteen, he's also set onfire by Damien and watched Pip get spit on,
109 - Starvin Marvin
Butters is not seen in this episode.
110 - Mr.Hankey, the Christmas Poo
Butters appears in the school Christmas play.  Background only.
111 - Tom's Rhinoplasty
Butters appears here in front of Kenny in the lunch line.
112 - Mecha-Streisand
He's seen with the other kids digging for arrow heads.  He also laughs at Pip.
113 - Cartmans Mums a Dirty Slut (1)
Butters does not appear in this episode.
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