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459

SYMBOLS*

A Richardson A value (22)

Alk Einstein coefficient for spontaneous emission (70)

A Dimensionless ion saturation current density (233)

a Linear dimension

aO Bohr radius

Blk Einstein coefficient for stimulated emission (70)

Bkl Einstein coefficient for absorption (70)

b Impact parameter (55)

Co Constant specifying frequency shift in the Stark effect

c Velocity of light

D Diffusion coefficient

Da Diffusion coefficient for atoms in their own vapor (29)

De Electron diffusion coefficient

DeA DeC Electron diffusion coefficient near the anode and cathode

DE(E) Electron diffusion coefficient for energy space (153)

Di Ion diffusion coefficient (171)

DiA DiC Ion diffusion coefficients near the anode and cathode

D(mi) Dissociation energy of molecular ions (122)

D(m) Molecular dissociation energy (140)

DeT Electron thermal diffusion coefficient (257)

Dn Diffusion coefficient for electrons in velocity space

Dn a b Diffusion tensor components (106)

D1 Diffusion coefficient for atoms excited to the first level (148)

d Interelectrode spacing (6)

_______________

*Numbers in parenthesis indicate pages where symbol is used or defined.

460

E Thermoelectric emf (1)

E Electric field intensity

EC Field intensity at the cathode (298)

Eea Electron affinity (31)

Eion Ionization energy for a ground state atom

En,ion Ionization energy for an atom with excitation energy En

Ei,j,k Excitation energies of levels i, j, k

Ekl Energy difference of atomic levels k and l

E Energy (kinetic) of a particle

D E Change in kinetic energy with collision (per unit time)


e Electronic charge

erf(z) Error function (193)


F Force


FL Lorentz force

f Average vibration frequency of adsorbed particle (30)


f(n ) Velocity distribution function (81)

fe(n ) Electron velocity distribution function

fi(n ) Ion velocity distribution function (179)

fkl Oscillator strength for transition between levels k and l (61)

fm(n ) Maxwellian velocity distribution function using the cathode temperature (49)

fM(n ) Maxwellian velocity distribution function (81)

fm e, fk e Correction to Mathiessen’s behavior in the transport

coefficients (103)

fo(Ei) Fermi-Dirac distribution function

g Kramer-Gaunt factor

g Relative velocity before collision (55)

g’ Relative velocity after collision (55)

ga Statistical weight of an atom (33)

gi Statistical weight of an ion (33)

461

gk Statistical weight for level k of the atom (62)

H Magnetic field strength

H Heat of desorption (31)

Hint Heat of absorption function defined by equation 2.9.4 (39)

h h Planck’s constant (h = h/2p )

I Current

Ie(Ii) Dimensionless electron (ion) current (271)

I{ } Collision term (85)

Iab Collisional term of the kinetic equation for particle a - particle b interactions (106)

Iee Collisional term of the kinetic equation for electrons -electron interactions (105)

I Net rate of transitions from the discrete level to the continuum (127)

I Total current (225)

I 0 1 Atomic transition rate from the ground state to the first excited state (151)

I is Ion saturation current to probe (227)

i Particle flux (115)

ia Random flux of atoms (359)

ie(ii) Electron (ion) flux (209)

(ieva)TEquilibrium atom evaporation from a surface (27)

iE Electron flux in energy space (153)

ik Flow or atoms excited to the k level (129)

ip, ipe(E)Flux energy distribution for emission from the plasma (184)

is(E) Flux energy distribution for emission from the electrode (183)

J Dimensionless current density

J = je - jiCurrent density

jb Beam current density (413)

462

je = -eieElectron current density (87)

jeC Electron current density emitted by the cathode (268)

jes Electron saturation current density (226)

jev Current density for emission from a virtual cathode

jI = eiiIon current density (228)

jiC Ion current density emitted by the cathode (268)

jis Ion emission current from the cathode (379)

jo Extinction current density (331)

js Electron emission current from the cathode (379)

jsC Schottky current at the cathode (298)

js0 Saturation thermionic emission current in the absence of an electric field (25)

j1 Current density at the knee of the I-V curve (334)

Ke(T) Electron thermal diffusion ratio (88)

Ki(T) Ion thermal diffusion ratio (267)

Kv(s) MacDonald function (155)

k Boltzmann constant

kO Absorption coefficient at a spectral line center (144)

k(w ) Radiation absorption coefficient (142)

L Length

LD Debye length (radius) (58)

LE Electron energy relaxation length (186)

Li Length of ionization region (355)

Llk(w )Spectral distribution over a spectral line (73)

L1 De-excitation length for first excited state de-excitation (149)

l Mean free path

l Arbitrary quantum number

la Mean free path for atoms in their own vapor

463

le Electron mean free path (6)

ls Beam breakup length (414)

li Ion mean free path

lp Mean free path for momentum change (96)

M MaAtomic mass

M Mi Mass of the ion

m Mass of the electron (8)

m Magnetic quantum number

ma mb Masses of particles a and b (55)

mab Reduced mass of colliding particles a and b (55)

N Surface concentration of adsorbed particles (30)

Na Atom density in a gas (21)

NA Density of cesium atoms near the anode (270)

Na(T) Equilibrium atom density at temperature T

Na¥ Atom density far from probe (237)

Na Nb Number of particles a or b per unit volume (56)

Ne(T) Coefficient of the Saha equation (121)

Nk Density of excited atoms in state k (70)

Nk(T) Equilibrium density of excited atoms in state k

Nmax The greatest surface density possible for adsorbed monolayer(32)

Nn(cont.) Population of level n in equilibrium with the continuum (132)

n Principal quantum number

n Particle (plasma) density

nA(nC) Plasma density near the anode (cathode)

ne(ni) Electron (ion) density

464

ne(T) Equilibrium density of electrons

nm Maximum of the plasma density distribution

n¥ Density of plasma far from the probe (227)

n0 Density of charged particles at the boundary of a quasi-neutral plasma and a space charge layer

n(E) Electron energy distribution

nM(E) Maxwellian electron energy distribution

PL Load power

PL(max)Maximum power along a volt-ampere characteristic (9)

Pi Rate of energy expenditure in forming ions (8)

Pm Fitting parameter in expression for cesium vapor pressure (38)

Pmax Maximum power (278)

P Pressure

P Momentum

D P Charge in momentum due to a collision

Pa(Pe, Pi)Atom (electron, ion) partial pressure (350)

Pra b Pressure tensor of the rth component of a plasma (357)

PBa Barium vapor pressure (42)

PCs Cesium vapor pressure (38)

PO2 Oxygen pressure (43)

PT Equilibrium thermodynamic pressure (27)

PO Standard pressure (27)

Q Total elastic scattering cross section (56)

Qea Electron atom scattering cross section (60)

Qia Ion atom cross section (61)

Qion Ionization cross section (61)

Qk, ionCross section for ionization from level k (61)

465

Qkl Excitation cross section for transition from level k to level 1 (61)

Qp Momentum transfer cross section (59)

Qred Qred(ph)Radiative recombination cross section (62, 72)

Q0 1 Cross section for atomic transition from the ground state to the first excited state (154)

qA Electron heat of condensation at the anode (345)

qa Flux density for atomic thermal conduction

qe Total energy flux density for electrons

qe(k) Flux density of electron kinetic energy

R Gas constant

R Dimensionless parameter for space charge volt-ampere curves (50)

RL Load resistance

Re Collisional force on the electron (105)

Rea Collisional resistive force on electrons because of collisions with atoms (348)

Rei Collisional resistive force due to electron-ion interaction (348)

Ria Collisional resistive force on ions because of collisions with atoms (348)

Rie Electron-ion friction force (267)

Ry Rydberg unit (68)

R+ Ion radius (31)

r Coordinate

r Average flow of electron kinetic energy (16)

r Coefficient for reflection of radiation from the electrode

@r Average quantum mechanical reflection coefficient (22)

ra rbRadii of rigid spheres a and b (56)

ra Cyclotron radius (91)

466

re Exponent for the energy dependence of the mean free path

ri Quantum mechanical reflection coefficient (21)

rkin Kinetic reflection coefficient (22)

rmin Distance of closest approach (57)

r1 r2 Plasma-electrode interface reflection coefficients (18)

S Energy flux density

dSh Decrease in entropy of the heat source (2)

dSc Increase in entropy of the heat sink (2)

SA Heat flux delivered to the anode (24)

Sa Atom thermal flux (268)

D Sab Energy transfer rate between particles a and b (110)

Se Electron energy flux (210, 268)

Seva Electron cooling flux from the cathode (8)

Sek Electron kinetic energy flux density (87)

Skl Absolute line intensity (254)

D Slk Energy emitted in a spectral line per unit volume of plasma (72)

S3/2(n) Sonine polynomials (97)

SP Probe surface area (225)

Srad Radiant energy flux (9)

S(x) Radiation from a plasma column (248)

S(w ) Radiation flux density

D S(w ) Energy radiated per unit volume per unit time

T Temperature

TA(TC)Temperature of the anode (cathode)(6)

TR Cesium reservoir temperature (38)

TCs Temperature corresponding to cesium vapor pressure

Te Electron temperature

TeA(TeC)Electron temperature near the anode (cathode)(l0)

Tc Cold junction temperature (1)

467

Th Hot junction temperature (1)

Ti Ion temperature

Tl Characteristic temperature for Z—level population (254)

t Time

u Barrier potential distribution in the Schottky effect (25)

ue ui Dimensionless electron (ion) mobility (271)

u1 Potential of an applied electric field (25)

u2 Potential energy of mirror image force (25)

V Voltage

V Volume

D V Contact potential difference (24)

V Dimensionless potential (49, 168, 271)

VA Dimensionless anode sheath drop (271)

D VA Change in the anode potential barrier due to the passage of current (269)

VB Height of a potential barrier (5)

VC Change in the cathode potential barrier due to the passage of current (269)

VTA(VTC)Equilibrium potential barrier near the anode (cathode) (269)

VL Load voltage (3)

Vd Diode voltage drop (47)

VdO Gap voltage drop at extinction (331)

Vex Extinction voltage (7)

Vig Ignition voltage (7)

Vm Maximum of space charge potential distribution (47)

VO Probe floating potential (222)

VOC Open circuit voltage (278)

VP Probe potential (224)

468

VP Dimensionless plasma drop (271)

Vqn Potential drop in quasi-neutral region of sheath (231)

Vsc Potential drop in space charge sheath (231)

v Velocity

@va Average velocity of atoms in their own vapor (29)

va vb Velocities of particles a and b before collision (55)

va vb Velocities of particles a and b after collision (55)

vc Velocity of center of mass (55)

vd Drift velocity (350)

vde(vdi) Electron (ion) drift velocity (109)

vda(vdm)Atom (molecule) drift velocity

ve(vi) Electron (ion) velocity (380)

@vi Velocity component perpendicular to a barrier (21)

vx Velocity in the x-direction (49)

W Potential barrier for valence electrons of a metal (20)

W Dimensionless electron heat flux (271)

Wk,ion Rate of ionization from level k (127)

Wkl Rate of transition between levels k and 1 (126)

Wmkme Probability for absorption with transition from level in to level mk (70)

Wmemksp Probability for spontaneous transition from level in to level mk (70)

Wmkmest Probability for stimulated transition from level in to level mk (70)

wa Probability for desorption as an atom (33)

wi+ Probability for desorption as an ion (33)

wk Probability for desorption of an atom in the kth excited state (34)

wk, ionProbability of ionization from level k (124)

469

wk,l Probability of excitation from levels k to 1 (124)

wlk(ph)Probability for photon emission from the plasma

w Distance (25)

wm Position of space charge potential maximum (47)

wO Distance to the potential maximum (25)

x Distance (49)

xm Distance (49)

z Charge on the nucleus

za Partition function for particle a (16, 121)

zkl Rate of transfer of atomic electrons from the kth to the lth level per unit volume per unit time

zT Dimensionless thermoelectric figure of merit (16)

a Thermoelectric emf (16)

a Collisions recombination coefficient

a Accommodation coefficient (27)

a Fine structure constant (73)

a Ion to electron cathode emission ratio (380)

a k Coefficient for collisions recombination to level k (125)

a n a p Seebeck coefficients (1)

b Dimensionless patch coefficient (25)

b Radiative recombination coefficient

b Angle defined on page 57

b Dimensionless spacing (272)

b Anomalous-Schottky-effect coefficient (300)

b eff Effective recombination coefficient (130)

b k Coefficient for optical recombination to level k (123)

G Net rate of ionization-recombination (126)

G ion Rate of ionization

470

G rec Rate of recombination

G (z) Gamma function (75)

g Dimensionless relaxation ratio (5.5.16)

g e g i Dimensionless coefficients for electron and ion currents from the plasma (7.l.30)(7.l.26)

g m ,k,k Transport coefficient corrections due to electron-electron collisions (96)

g o Spectral line half width (76)

g o Dimensionless drift velocity parameter in (6.2.14) for ions to the plasma boundary

D l Quantum defect (69)

d (x) Degree of deviation from ionization equilibrium (356)

d (w ,x)Radiant flux (142)

e Effective system thermal emissivity (9)

e A(e C)Emissivity of the anode (cathode) (9)

h Efficiency (5)

h Viscosity (289)

h max Maximum efficiency along a volt-ampere characteristic (9)

h C Carnot efficiency (4)

q Relative coverage of a surface by adsorbed atoms (32)

q o Scattering angle in center of mass system (55)

k Thermal conductivity (16)

k a Atomic thermal conductivity (294)

k e Electron thermal conductivity

k ea Thermal conductivity due to electron-atom collisions

k ei Thermal conductivity due to electron-ion collisions

k i Ion thermal conductivity (349)

l lk Emission wavelength (146)

m Chemical potential (16, 168)

471

m A Plasma chemical potential near the anode (269)

m C Plasma chemical potential near the cathode (269)

m e Electron mobility (88)

m ea Electron mobility with electron-atom collisions

m ea Electron mobility with electron-ion collisions

m i Ion mobility (171)

n Dimensionless density (271)

n ab Collision frequency for particles a and b (112)

n k Level population relative to equilibrium (135)

n kl Frequency of photon from transition from levels k to 1 (69)

n pl Plasma frequency (221)

x Dimensionless distance variable (49, 271)

x D Dimensionless distance (168, 380)

x d Dimensionless spacing (381)

x 0 Dimensionless distance (49)

P A Peltier coefficient for the anode (24)

P C Peltier coefficient for the cathode (23)

r Space charge density (179)

r (w ) Density of electromagnetic radiation (70)

S Total scattering cross section

S p Momentum transfer cross section

s Stefan-Boltzmann constant (9)

s Electrical conductivity (16)

s Differential scattering cross section (56)

s 0 Ionization cross section (139)

t Mean free time (56)

t Ratio of anode to cathode temperature

472

t E Energy relaxation time (57, 186)

t e t iDimensionless electron (ion) temperature (271)

t i Effective time for ionization

t p Momentum relaxation time (57)

t Eab Energy relaxation time for collisions between particles a and b (108)

t Qab Effective energy exchange time for collisions between particles a and b (108)

t 0 1 Time for excitation to the resonance level

f Work function (170)

@f Average work function of patches (26)

D f Charge in work function due to adsorbed species (31)

D f Reduction of the work function due to the Schottky effect (25)

f A(f C)Anode (cathode) work function

f Ba Work function of pure barium (47)

f int Surface coverage function defined by equation 2.9.5 (39)

f max Maximum work function of patches (26)

f min Minimum work function of patches (26)

f O Vacuum (bare) work function (31)

y Dimensionless potential

y A(y C, y 0)Dimensionless anode (cathode, diode) potential drop

y Ordinary potential, defined on page 48

D y Change in sheath potential drop compared to equilibrium

y A(y C, y 0)Potential drop across the anode (cathode, diode)

y T Equilibrium sheath potential drop

W lk Emission line width (144)

dW dW 0Element of solid angle (56)

w Frequency

473

w c Cyclotron frequency (85)

w kl Radiation angular frequency (2p n ) in the discrete spectra (69)

w p Plasma frequency

D w t Total line broadening (251)

w th Continuum threshold frequency (255)

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