Aviation Gasoline 100 & 100 Low Lead - material safety data sheet

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`Chevron Aviation Gasoline100 and 100 Low Lead`MSDS: 2647 Revision #: 15 Revision Date: 05/04/93 �� 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION �� AVIATION GASOLINE �� PRODUCT NUMBER(S): CPS200205�� CPS200239�� CPS200285 �� CPS200456 �� CPS321811 �� COMPANY IDENTIFICATION �� EMERGENCY TELEPHONE NUMBERS�� Chevron USA Products Company �� HEALTH (24 hr): (800)231-0623 or��
Environmental, Safety, and Health �� (510)231-0623 (International) �� 575 Market St., Room 2900 �� TRANSPORTATION (24 hr): CHEMTREC�� San Francisco, CA �94105-2856 �� (800)424-9300 or (202)483-7616�� PRODUCT INFORMATION: (800)822-5823 MSDS Requests �� (510)242-5357 Technical �� 2. COMPOSITION/INFORMATION ON INGREDIENTS �� COMPOSITION COMMENT: �� All the components of this material are on the Toxic Substances Control ��
Act Chemical Substances Inventory. �� The proportion compositions are given to allow for the various ranges �� of the components present in the whole product and may not equal 100%. �� 100.0 %�� AVIATION GASOLINE �� CONTAINING �� COMPONENTS �� AMOUNT �� LIMIT/QTY �� AGENCY/TYPE �� GASOLINE (GENERIC) �� 100.0% �� 300ppm �� ACGIH TWA ��
�� 1480 mg/m3�� ACGIH STEL �� 300ppm �� OSHA PEL �� INCLUDING �� ETHYL BENZENE �� Chemical Name: BENZENE, ETHYL- �� CAS100414 �� < �4.0%�� 434 mg/m3 �� ACGIH TWA �� 543 mg/m3�� ACGIH STEL �� 435 mg/m3�� OSHA PEL �� 1,000 LBS�� CERCLA 302.4 RQ �� XYLENE-O ��
Chemical Name: BENZENE, 1,2-DIMETHYL- �� CAS95476 �� < �4.3%�� 434 mg/m3 �� ACGIH TWA �� 651 mg/m3�� ACGIH STEL �� 435 mg/m3�� OSHA PEL �� 1,000 LBS�� CERCLA 302.4 RQ �� XYLENE-P �� Chemical Name: BENZENE, 1,4-DIMETHYL- �� CAS106423 �� < �4.3%�� 434 mg/m3 �� ACGIH TWA �� 651 mg/m3�� ACGIH STEL �� 435 mg/m3�� OSHA PEL �� 1,000 LBS�� CERCLA 302.4 RQ ��
XYLENE-M �� Chemical Name: BENZENE, 1,3-DIMETHYL- �� CAS108383 �� < �8.8%�� 434 mg/m3 �� ACGIH TWA �� 651 mg/m3�� ACGIH STEL �� 435 mg/m3�� OSHA PEL �� 1,000 LBS�� CERCLA 302.4 RQ �� TOLUENE �� Chemical Name: TOLUENE �� CAS108883 �� < 14.0%�� 377 mg/m3 �� ACGIH TWA �� 100ppm �� OSHA PEL �� 300 ppm�� OSHA CEILING �� 1,000 LBS�� CERCLA 302.4 RQ ��
�� HEXANE �� Chemical Name: HEXANE �� CAS110543 �� < �5.0%�� 176 mg/m3 �� ACGIH TWA �� 3500 mg/m3�� ACGIH STEL �� 1800 mg/m3�� OSHA PEL �� CYCLOHEXANE �� Chemical Name: CYCLOHEXANE �� CAS110827 �� < �2.4%�� 1030 mg/m3 �� ACGIH TWA �� 1050 mg/m3�� OSHA PEL �� 1,000 LBS�� CERCLA 302.4 RQ ��
BENZENE �� Chemical Name: BENZENE �� CAS71432 �� < �4.9%�� 32 mg/m3 �� ACGIH TWA �� 1ppm �� OSHA PEL �� 25 ppm�� OSHA CEILING �� 10 LBS�� CERCLA 302.4 RQ �� Refer to the OSHA Benzene Standard (29 CFR 1910.1028) for detailed �� training, exposure monitoring, respiratory protection and medical �� surveillance requirements before using this product. �� TETRAETHYLLEAD �� Chemical Name: TETRAETHYL LEAD ��
CAS78002 �� < �4.0ML/GAL �0.1 mg/m3�� ACGIH TWA �� 0.075 mg/m3�� OSHA PEL �� 10 LBS�� CERCLA 302.4 RQ �� 100 LBS�� SARA 302 TPQ �� 10 LBS�� SARA 304 RQ �� TLV �- Threshold Limit Value�� TWA - Time Weighted Average �� STEL - Short-term Exposure Limit�� TPQ - Threshold Planning Quantity �� RQ�� - Reportable Quantity �� CPS - CUSA Product Code �� CC�� - Chevron Chemical Company�� CAS - Chemical Abstract Service Number�� 3. HAZARDS IDENTIFICATION ��
�� ************* EMERGENCY OVERVIEW * �� Blue-green liquid �� - EXTREMELY FLAMMABLE �� - HARMFUL OR FATAL IF SWALLOWED - CAN ENTER LUNGS �� AND CAUSE DAMAGE �� - VAPOR HARMFUL �� - MAY CAUSE EYE AND SKIN IRRITATION �� - LONG-TERM EXPOSURE TO VAPOR HAS CAUSED CANCER IN �� LABORATORY ANIMALS ��
�� - CONTAINS LEAD �� - KEEP OUT OF REACH OF CHILDREN �� ******************** �� POTENTIAL HEALTH EFFECTS �� EYE: �� This substance is slightly irritating to the eyes and could cause �� prolonged (days) impairment of your vision. �The degree of the injury will �� depend on the amount of material that gets into the eye and the speed and �� thoroughness of the first aid treatment. �Eye contact with the vapors, �� fumes, or spray mist from this substance could also cause similar signs �� and symptoms. �This hazard evaluation is based on the data from similar ��
materials. �� SKIN: �� Prolonged or frequently repeated contact may cause the skin to become �� cracked or dry from the defatting action of this material. �� INGESTION: �� This substance is slightly toxic to internal organs if swallowed. �The �� degree of injury will depend on the amount absorbed from the gut. �The �� target organ(s) is the nervous system. �Because of the low viscosity of �� this substance, it can directly enter the lungs if it is swallowed (this �� is called aspiration). �This can occur during the act of swallowing or �� when vomiting the substance. �Once in the lungs, the substance is very �� difficult to remove and can cause severe injury to the lungs and death. �� This hazard evaluation is based on data from similar materials. ��
INHALATION: �� This substance is slightly toxic to internal organs if inhaled. �The �� degree of injury will depend on the airborne concentration and duration of �� exposure. �The target organ(s) is the nervous system. �Inhalation of �� gasoline vapor at airborne concentrations exceeding 1000 ppm may cause �� signs and symptoms of central nervous system effects such as headache, �� dizziness, loss of appetite, weakness and loss of coordination. �Vapor �� concentrations in excess of 5000 ppm may cause loss of consciousness, coma �� and death. �Brief exposures to high vapor concentrations may also cause �� pulmonary edema and bronchitis. �Intentional exposures to excessively high �� concentrations (e.g., when used as a drug of abuse) have been reported to �� result in clinical manifestations that may include convulsions, delirium, �� and hallucinations. �These manifestations are not known to occur following ��
accidental inhalation of gasoline vapor during normal operations. �This �� hazard evaluation is based on data from similar materials. �� SIGNS AND SYMPTOMS OF EXPOSURE: �� EYE: �May include pain, tears, swelling, redness, and blurred vision. �� INGESTION: �May include one or more of the following: �headache, �� dizziness, loss of appetite, weakness and loss of coordination. �� 4. FIRST AID MEASURES �� EYE: �� Flush eyes immediately with fresh water for at least 15 minutes while ��
holding the eyelids open. �Remove contact lenses if worn. �No additional �� first aid should be necessary. �However, if irritation persists, see a �� doctor. �� SKIN: �� No first aid procedures are required. �As a precaution, wash skin �� thoroughly with soap and water. �Remove and wash contaminated clothing. �� INGESTION: �� If swallowed, give water or milk to drink and telephone for medical �� advice. DO NOT make person vomit unless directed to do so by medical �� personnel. �If medical advice cannot be obtained, then take the person and �� product container to the nearest medical emergency treatment center or �� hospital. �� INHALATION: ��
If respiratory irritation or any signs or symptoms as described in this �� document occur, move the person to fresh air. �If any of these effects �� continue, see a doctor. �� NOTE TO PHYSICIANS: �� Ingestion of this product or subsequent vomiting can result in aspiration �� of light hydrocarbon liquid which can cause pneumonitis. �� 5. FIRE FIGHTING MEASURES �� FLAMMABLE PROPERTIES �� FLASH POINT: (P-M) < -49F �(-45C) ��
AUTOIGNITION: 824F �(440C) �� FLAMMABILITY LIMITS (% by volume in air): �Lower: 1.3 �Upper: 7.1 �� EXTINGUISHING MEDIA: �� Fire Fighting Foam: Alcohol Resistant Type (AR) �� AFFF, CO2, Dry Chemical. �� NFPA RATINGS: Health 1; Flammability 3; Reactivity 0. �� FIRE FIGHTING INSTRUCTIONS: �� This product presents an extreme fire hazard. �Liquid very quickly �� evaporates, even at low temperatures, and forms vapor (fumes) which can �� catch fire and burn with explosive violence. �Invisible vapor spreads �� easily and can be set on fire by many sources such as pilot lights, �� welding equipment, and electrical motors and switches. ��
For fires involving this material, do not enter any enclosed or confined �� fire space without proper protective equipment. �This may include �� self-contained breathing apparatus to protect against the hazardous �� effects of normal products of combustion or oxygen deficiency. �Read the �� entire document. �� COMBUSTION PRODUCTS: �� Normal combustion forms carbon dioxide and water vapor; incomplete �� combustion can produce carbon monoxide. �� 6. ACCIDENTAL RELEASE MEASURES ��
CHEMTREC EMERGENCY NUMBER (24 hr): (800)424-9300 or (202)483-7616 �� ACCIDENTAL RELEASE MEASURES: �� Eliminate all sources of ignition in vicinity of spill or released vapor. �� Clean up small spills using appropriate techniques such as sorbent �� materials or pumping. �Where feasible and appropriate, remove contaminated �� soil. �Follow prescribed procedures for reporting and responding to larger �� releases. �This material is considered to be a water pollutant and �� releases of this product should be prevented from contaminating soil and �� water and from entering drainage and sewer systems. �� U.S.A. regulations require reporting spills of this material that could �� reach any surface waters. �The toll free number for the U.S. Coast Guard ��
National Response Center is (800) 424-8802. �� 7. HANDLING AND STORAGE �� HANDLING AND STORAGE: �� Never siphon gasoline by mouth. �READ AND OBSERVE ALL PRECAUTIONS ON �� PRODUCT LABEL. �Use only as a motor fuel. �Do not use for cleaning, �� pressure appliance fuel, or any other such use. �DO NOT USE OR STORE near �� flame, sparks or hot surfaces. �USE ONLY IN WELL VENTILATED AREA. �Keep �� container closed. �DO NOT TRANSFER LIQUID TO AN UNLABELED CONTAINER. �DO �� NOT weld, heat or drill container. �Replace cap or bung. Emptied container ��
still contains hazardous or explosive vapor or liquid. �AVIATION FUEL �� SHOULD BE FILTERED DURING TRANSFER INTO FUEL TANKS. �� 8. EXPOSURE CONTROLS/PERSONAL PROTECTION �� PERSONAL PROTECTIVE EQUIPMENT �� EYE/FACE PROTECTION: �� Do not get this material in your eyes. �Eye contact can be avoided by �� wearing chemical goggles. �� SKIN PROTECTION: �� No special skin protection is usually necessary. �Avoid prolonged or ��
frequently repeated skin contact with this material. �Skin contact can be �� minimized by wearing protective clothing. �� RESPIRATORY PROTECTION: �� No special respiratory protection is normally required. �However, if �� operating conditions create airborne concentrations which exceed the �� recommended exposure standards, the use of an approved respirator is �� required. �Refer to the OSHA Benzene Standard to determine what type of �� respirator is required based on exposure levels. �� ENGINEERING CONTROLS: �� Use this material only in well ventilated areas. �� 9. PHYSICAL AND CHEMICAL PROPERTIES ��
�� PHYSICAL DESCRIPTION: �� Blue-green liquid �� pH: �� NDA �� VAPOR PRESSURE:�� 5.5 - 7.0 PSI �@ 100F (Range) �� VAPOR DENSITY �� (AIR=1):�� NDA �� BOILING POINT:�� 100 - 338F �(Range) �� FREEZING POINT:�� Below -60C �� MELTING POINT:�� NA �� SOLUBILITY:�� Soluble in hydrocarbons; insoluble in water. �� SPECIFIC GRAVITY: �0.7 ��
DENSITY:�� NDA �� EVAPORATION RATE: �NDA �� PERCENT VOLATILE �� (VOL):�� NDA �� 10. STABILITY AND REACTIVITY �� HAZARDOUS DECOMPOSITION PRODUCTS: �� NDA. �� CHEMICAL STABILITY: �� Stable. ��
CONDITIONS TO AVOID: �� No data available. �� INCOMPATIBILITY WITH OTHER MATERIALS: �� May react with strong oxidizing agents, such as chlorates, nitrates, �� peroxides, etc. �� HAZARDOUS POLYMERIZATION: �� Polymerization will not occur. �� 11. TOXICOLOGICAL INFORMATION �� EYE EFFECTS: ��
No product toxicology data available. �The hazard evaluation was based on �� data from similar materials. �� SKIN EFFECTS: �� No product toxicology data available. �The hazard evaluation was based on �� data from similar materials. �� ACUTE ORAL EFFECTS: �� No product toxicology data available. �The hazard evaluation was based on �� data from similar materials. �� ACUTE INHALATION EFFECTS: �� No product toxicology data available. �The hazard evaluation was based on �� data from similar materials. �� ADDITIONAL TOXICOLOGY INFORMATION: �� Lifetime inhalation of whole gasoline vapor has caused increased liver ��
tumors in female mice. �The mechanism of this response is still being �� investigated but it is thought to be an epigenetic process unique to the �� female mouse. �Inhalation exposure to whole gasoline vapor also caused �� kidney damage and eventually kidney cancer in male rats. �No other animal �� model studied has shown these adverse kidney effects and there is no �� physiological reason to believe that they would occur in man. �� The data above is obtained from studies sponsored by the American �� Petroleum Institute (API). �� This product contains benzene. �The OSHA Benzene Standard (29 CFR �� 1910.1028) contains detailed requirements for training, exposure ��
monitoring, respiratory protection and medical surveillance triggered by �� the exposure level. �Refer to the OSHA Standard before using this product. �� Repeated or prolonged breathing of benzene vapors has been associated with �� the development of chromosomal damage in experimental animals and various �� blood diseases in humans ranging from aplastic anemia to leukemia (a form �� of cancer). All of these diseases can be fatal. �No birth defects have �� been shown to occur in pregnant laboratory animals exposed to doses not �� toxic to the mother. �However, some evidence of fetal toxicity such as �� delayed physical development has been seen at such levels. The available �� information on the effects of benzene on human pregnancies is inadequate �� but it has been established that benzene can cross the human placenta. ��

This product contains toluene. Toluene has been reported to decrease �� immunological responses in test animals. It has also been reported that �� when young rats were exposed to 1000 ppm toluene for 14 hours daily, for �� two weeks, irreversible hearing loss was detected. The same daily exposure �� to 700 ppm for as long as 16 weeks was without effect. Since the level �� necessary to produce hearing loss is greater than 7 times the ACGIH �� TLV-TWA for toluene, worker exposures at or below 100 ppm is not expected �� to cause any adverse effects. �There are also reports that chronic solvent �� abusers (glue sniffers, solvent huffers) who deliberately inhale high �� concentrations (several thousand ppm) of toluene for prolonged periods (up �� to ten hours/day) have suffered liver, kidney and brain damage. Toluene �� may also cause mental and/or growth retardation in the children of female �� solvent abusers who directly inhale toluene when they are pregnant. ��
Toluene caused growth retardation in rats when administered at doses that �� were toxic to the mothers (1500 ppm). �Concentrations of up to 5000 ppm �� did not cause birth defects. There were no effects in the offspring at �� doses that did not intoxicate the pregnant rats. The exposure level at �� which no effects were seen (No Observed Effect Level, NOEL) is 750 ppm. We �� recommend that the precautions outlined in this MSDS be followed to keep �� toluene concentrations below the recommended exposure standards. �� This product contains xylene, a chemical that has been reported to cause �� developmental toxicity in rats and mice exposed by inhalation during �� pregnancy. �The effects noted consisted of delayed development and minor �� skeletal variations; additionally, when pregnant mice were exposed by �� ingestion to a level that killed nearly one-third of the test group, ��
lethality (resorptions) and malformations (primarily cleft palate) �� occurred. �Malformations have not been reported following inhalation �� exposure. �Because of the very high levels of exposure used in these �� studies, we do not believe that their results imply an increased risk of �� reproductive toxicity to workers exposed to xylene levels at or below the �� exposure standard. �� Xylene has given negative results in several mutagen testing assays �� including the Ames assay. �In a cancer study sponsored by the National �� Toxicology Program (NTP), technical grade xylene gave no evidence of �� carcinogenicity in rats or mice dosed daily for two years. �� Mixed xylenes have been shown to cause probable hearing loss in rats ��
exposed to 800 ppm in the air for 14 hours per day for six weeks. �� Although no information is available for lower concentrations, other �� chemicals that cause hearing loss in rats at relatively high �� concentrations do not cause hearing loss at low concentrations. �Men �� exposed to 135 to 400 ppm of m-xylene for over 3 hours per day for a total �� of 4 days showed no hearing loss. �Worker exposure to xylenes at the �� permissible exposure limit (100 ppm, time-weighted average) is not �� expected to cause hearing loss. �� This product contains n-hexane. �Prolonged or repeated skin contact or �� breathing of vapors may cause nerve damage characterized by progressive �� weakness and numbness in the arms and legs. �Recovery ranges from no �� recovery to complete recovery depending upon the severity of the nerve ��
damage. �� 12. ECOLOGICAL INFORMATION �� ECOTOXICITY: �� No data available. �� ENVIRONMENTAL FATE: �� No data available. �� 13. DISPOSAL CONSIDERATIONS ��
�� DISPOSAL CONSIDERATIONS: �� Place contaminated materials in disposable containers and dispose of in a �� manner consistent with applicable regulations. �Contact local �� environmental or health authorities for approved disposal of this �� material. �� 14. TRANSPORT INFORMATION �� The description shown may not apply to all shipping situations. ��
Consult 49CFR, or appropriate Dangerous Goods Regulations, for �� additional description requirements (e.g., technical name) and �� mode-specific or quantity-specific shipping requirements. �� DOT SHIPPING NAME: GASOLINE �� DOT HAZARD CLASS: 3 (FLAMMABLE LIQUID) �� DOT IDENTIFICATION NUMBER: UN1203 �� DOT PACKING GROUP: II �� 15. REGULATORY INFORMATION ��
SARA 311 CATEGORIES:�� 1. �Immediate (Acute) Health Effects: �YES�� 2. �Delayed (Chronic) Health Effects: �YES �� 3. �Fire Hazard: �� YES �� 4. �Sudden Release of Pressure Hazard: NO �� 5. �Reactivity Hazard: �� NO �� REGULATORY LISTS SEARCHED: �� 01=SARA 313 �� 11=NJ RTK �� 21=TSCA Sect 4(e)�� 02=MASS RTK �� 12=CERCLA 302.4�� 22=TSCA Sect 5(a)(e)(f) �� 03=NTP Carcinogen�� 13=MN RTK �� 23=TSCA Sect 6 �� 04=CA Prop 65-Carcin�� 14=ACGIH TWA �� 24=TSCA Sect 12(b)�� 05=CA Prop 65-Repro Tox �15=ACGIH STEL �� 25=TSCA Sect 8(a) ��
06=IARC Group 1�� 16=ACGIH Calc TLV�� 26=TSCA Sect 8(d) �� 07=IARC Group 2A�� 17=OSHA PEL �� 28=Canadian WHMIS�� 08=IARC Group 2B�� 19=Chevron TWA �� 29=OSHA CEILING �� 09=SARA 302/304�� 20=EPA Carcinogen �� 30=Chevron STEL �� 10=PA RTK �� The following components of this material are found on the regulatory �� lists indicated. �� BENZENE, ETHYL- �� is found on lists: �01,02,10,11,12,13,14,15,17,26,28, �� BENZENE, 1,4-DIMETHYL- �� is found on lists: �01,02,10,11,12,13,14,15,17,26,28, ��
BENZENE, 1,3-DIMETHYL- �� is found on lists: �01,02,10,11,12,13,14,15,17,26,28, �� TOLUENE �� is found on lists: �01,02,05,10,11,12,13,14,17,26,28,29, �� HEXANE �� is found on lists: �02,10,11,13,14,15,17,28, �� CYCLOHEXANE �� is found on lists: �01,02,10,11,12,13,14,17,26,28, �� BENZENE �� is found on lists: �01,02,03,04,06,10,11,12,13,14,17,20,28,29, �� TETRAETHYL LEAD �� is found on lists: �02,09,10,11,12,13,14,17,28, �� BENZENE, 1,2-DIMETHYL- ��
� is found on lists: �01,02,10,11,12,13,14,15,17,26,28, �� GASOLINE (GENERIC) �� is found on lists: �04,08,14,15,17,20, �� 16. OTHER INFORMATION �� NFPA RATINGS: Health 1; Flammability 3; Reactivity 0; �� (Least-0, Slight-1, Moderate-2, High-3, Extreme-4). �These values are �� obtained using the guidelines or published evaluations prepared by the �� National Fire Protection Association (NFPA) or the National Paint and �� Coating Association (for HMIS ratings). ��
�� REVISION STATEMENT: �� This Material Safety Data Sheet has been revised to comply with the �� ANSI Z400.1 Standard. �� Prepared according to the OSHA Hazard Communication Standard �� (29 CFR 1910.1200) and the ANSI MSDS Standard (Z400.1) by the Toxicology �� and Health Risk Assessment Unit, CRTC, P.O. Box 4054, Richmond, CA 94804 �� ______________________________ �� The above information is based on the data of which we are aware and is ��
believed to be correct as of the date hereof. �Since this information may �� be applied under conditions beyond our control and with which we may be �� unfamiliar and since data made available subsequent to the date hereof may �� suggest modification of the information, we do not assume any responsibil- �� ity for the results of its use. �This information is furnished upon �� condition that the person receiving it shall make his own determination �� of the suitability of the material for his particular purpose. �� NDA - No Data Available �� NA - Not Applicable �� REFRENCE |Chemical| Faisalmurad|Guest book| Comments|WEBMASTER|D.C.E.T|N.E.D uet|Title| Certificates|MAIL Us| ��
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