agent chemical name syn use /assay /comment
2-Antimetabolites cpds e str closely related to the substance used for metabolism
a-folic acid antagonists changes in 1-pteridine 2-PABA 3-glutamate 4-2,4 positions 5--9,10 positions 6-benzene ring substitution
`Diopterine & teropterine petroyl  -glutamyl - glutamyl glutamic acid  
Aminopterin 4-aminopteroyl glutamic acid  ** p-(2,4-diamino-6-pteridinyl methylamino) benzoyl glutamic acid  
Amethopterin (Methotrexate) (Lederle) 10-methylaminopterin or 4-amino-10-methylpteroyl glutamic acid  or p-(2,4-diamino-10methyl-6-pteridinylmethylamino) benzoyl glutamic acid   acute Leuckemia
b-purine antagonists ribose ,deoxyribose ,purine or pyrimidine >nucleoside >H3po4 >nucleotide >activation >nucleic acid
6-mercaptopurine (purinethiol , Leukerin) 6-mercaptopurine   test of impurity of hypoxanthine >spectrophotometrically ** antimetabolite of adenine *used in ttt of leuckemia
thioguanine 2-amino-6-mercaptopurine    
6-chloropurine     ttt of leuckemia
8-azaguanine 2-amino-6-hydroxy-8-azapurine   *all purine drv assayed by kjeldahl method *it is triazolo analogue of guanine
c-pyrimidine antagonists      
5-flurouracil   *ttt of certain solid tumours for w surgery or irradiation is not possible * it interfere e syn of DNA
cytosine HCl (Anacytin) 4-amino-2-hydroxypyrimidine HCl *cytosine interfere e syn of nu a *test of identity : cytosine HCl + sod hypochlorite + 1 dp of amm hydroxide >red col
Gemcitabine HCl (Gemzar) 2'-deoxy-2',2'-difluorocytidine,1-(2-oxo-4-amino-1,2-dihydropyrimidin-1-yl)-2-deoxy-2,2-difluororibose *it is antimetabolite to cytosine *used in ttt of lung cancer ,pancreatic adenocarcinoma *mech :inhibition of DNA synthesis
3-Hormones  
estrogens post menopausal breast cancer & cancer of prostate
tostesterone premenopausal breast cancer
corticosteroids > prednisone used in some cancer esp Hodgkin's disease & leukemias
estramustine 17-phosphate (estracyt) combination of N2 mustard with estradiol
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