Copper Pages

Piping and Copper Corrosion

Introduction

Corrosion Processes in Copper Water Piping

"Potable Water distributed within a building should be colorless, tasteless, odorless, and aesthetically acceptable to the occupants. It should contain no pathogenic organisms, biological forms, or concentrations of chemicals or metals which may be harmful to human health. In addition, the water should not be corrosive to or leave deposits on the distribution system through which it passes or may be retained."[1]

Corrosive Water can electrochemically destroy the potable water system of a building. Heated, high hardness water can produce heavy scale deposits in a system and significantly reduce its carrying capacity. Corrosion also adversely affects taste, color, and aesthetic appeal of water and can increase the concentration of toxic metals. Only when the problem of corrosion in potable water systems of buildings has been properly identified and the factors affecting its occurrence carefully analyzed is it possible to select the most advantageous method for correcting the problem."[2]

In Greater Vancouver we enjoy an abundant high quality water supply to furnish all of our water needs; drinking, bathing, cleaning, irrigation, fire suppression, commercial processes, etc. Also, we are amongst the greatest consumers of water in the world using an average of 289 gpd/person (1996)[3]. Few if any regions in the world enjoy such an abundant source of high quality water. However, our water is also extremely aggressive, rapidly corroding the materials that we use to convey this water to its outlets.

The corrosion nature of our soft water supply and the piping failures resulting from the corrosive attack by this water has been historically documented. In an article published by The B.C. Professional Engineer, by T. A. Maranda, July (1964) it was stated:

"The Corrosion of copper piping is gradually being recognized as inevitable in building domestic hot water systems in the Vancouver metropolitan area. It is therefore desirable to acquire a better understanding of corrosion phenomena and of available methods of inhibiting corrosion or, at least, of reducing corrosion rates in such systems.

More frequent failures in copper domestic hot water systems in the area have increased the growing concern for finding acceptable methods of controlling and preventing corrosion in these systems. In particular, systems with high daily hot water demands, which employ recirculation and which operate at a temperature in excess of 140° F., are subjected to high rates of corrosion. This is particularly valid for hospital, laundry, process, and school systems."

This list of susceptible buildings can be updated to include the many high and low rise multi-residential structures which employ central domestic hot water heating with a recirculation system. Without preventative maintenance, most, if not all, of these buildings will experience the need for a major piping repair or replacement at least once during the building lifetime. Such a repair/re-pipe is a costly undertaking generally requiring a lengthy intrusion of construction workers into people's living or working space. The construction process will also generate noise, dust, and disruption of water service as work progresses.

Knowledge of the causes of corrosion in the water pipe is thus critical in understanding the future implications of decisions made by owners, managers, contractors, and design engineers. There are currently available many alternatives and choices in the manner of repair and the materials to be used. Also, it is possible to treat the water in the building so that corrosion can be reduced thus increasing the longevity of the existing water piping.

[1] AWWA Task Group 2640P Water Quality Goals (E. L. Bean, Chairman), Journal AWWA, 60, 1317 (1968).

[2] "Potable Water Systems--Recognition of Cause Vital in Minimizing Corrosion", J.R. Myers and M.F. Obrecht, Materials Protection and Performance, p 41, Vol. 11, April (1972).

[3] Regional Water Supply Plan, June 1997 (Section 5-6)

The above excerpt was taken from a privately published report: "Water Pipe Corrosion in the GVRD", Duane M. Tilden, P.Eng., 1999. To obtain a copy of the full draft report please contact [email protected] for details.

1.The Copper Corrosion Dilemma

The difficulty many home, building owners and property managers face regarding the operation of copper based water supply systems, is that they will leak and eventually fail. When failures start to occur, there is a tendency to simply repair the problem by replacing the section of leaking pipe, and think no more about the problem until the next leak. In many buildings the beginning of pipe leaks and failures manifests slowly over time until there are many leaks.

When the piping system starts to leak, there may be considerable property damage resulting from the leak. Often these leaking pipes are buried in walls, or above finished ceilings, so the evidence of the leak is the ensuing water damage. When this occurs, the building supply system is generally shut off while the work proceeds. This requires removing water damaged areas, repairing the piping, and then refinishing the affected area. This all costs money. Often the cost of the damage from the leak will exceed the cost of the repair to the piping.

Generally speaking, when a water system starts to leak, the process is irreversible. This is because of the cumulative damage to the piping system caused by corrosion. The most insidious damaging form of this corrosion occurs as pinhole leaks. These are very tiny holes that eat through the pipe wall at a much faster rate than other forms of corrosion. It is from these tiny holes, and other forms of failure that the majority of piping failures occur.

In some cases (probably more than known) the affected buildings may start to experience leaks within 10 years, especially in hot water supply piping or the recirculation system (depending on the building design and system). In terms of longevity, this is not an acceptable time frame for a system which is difficult to access, and requires major repair strategies to fix. In the past and still to this day, many plumbers and contractors where under the impression that such copper systems would last a minimum of 50 years.

Copper used to be referred to as the "Gold Standard" of plumbing. However, history of copper plumbing systems in the Lower Mainland, and other areas of the world, demonstrate that this perception is not true, and that in some instances, copper piping can not withstand contact with certain chemical compositions of water.

2.The Corrosivity of GVRD Water

The cause of corrosion in its various forms is generally related to the interaction of the selected material with its environment. Poor design and installation are also contributing factors in examining corrosion failures. The study of copper corrosion failures in domestic water pipe installations is complicated by the unique, and changing chemistry of local domestic water supplies. Depending on the source of the water supplied by the local authority, a water source is generally categorized as either "aggressive" or "non-aggressive".

"The character or corrosiveness of the water supply is very significant. Water supplies characterized as soft waters, with high dissolved oxygen content, high carbon dioxide content, free chlorine concentrations and low hardness, are considered to be aggressive and corrosive; such soft waters tend to be acidic. The Greater Vancouver water supply is characterized as soft water and is aggressive.

Waters that are characterized as hard waters and contain high dissolved minerals can become aggressive and corrosive when softened. In the typical softening process, insoluble salts are replaced with soluble salts. The resultant water may be aggressive and can be corrosive to piping systems."[1]

[1]"Considerations to Reduce Corrosion of Copper Piping in Domestic Hot Water Systems in British Columbia", The BC Professional Engineer, September 1992.

The above excerpt was taken from a privately published report: "Corrosion of Copper Water Pipe in the GVRD pH or not pH? This is The Question, Duane M. Tilden, P.Eng. December, 2000 To obtain a copy of the full report please contact [email protected] for details.

3.Water Quality and Health Concerns

Copper is a naturally occurring metal in our environment and can be found to be present in our water, air and soil. It averages 50 ppm in the earth's crust, and about 4 ppb in lakes and rivers. Soil generally contains levels between 2 to 250 ppm with levels of 7000 ppm around copper production facilities. Copper levels in drinking water average 20 to 75 ppb with levels of 1 ppm (1000 ppb) found in many households. Copper is also naturally found in food and drink and is considered an essential nutrient at low levels, with average daily intake of about 1 milligram/day[1].

Human Health

The EPA (Environmental Protection Agency) in the United States has determined that copper should be limited to 1 ppm in lakes and streams and that drinking water should not contain more than 1.3 ppm[2]. Current Canadian guidelines[3] for copper levels in drinking water are set at 1.0 ppm MAC (Maximum Acceptable Concentration) at the point of consumption.

In high dosages (30 ppm) with exposure limited to once, consumption of copper has been linked to gastrointestinal upsets[4] such as vomiting, diarrhea, stomach cramps and nausea[5]. At a dosage rate of 3 ppm for an exposure of 9 months copper has been attributed to liver damage in infants. The severity of copper intoxication can be expected to increase with both level and length of exposure. Other symptoms of heavy metal intoxication include; mental confusion, pain in muscles and joints, headaches, short-term memory loss, gastrointestinal upsets, food sensitivities and allergies, vision problems, chronic fatigue, etc[6].

Exposures to copper in concentrations greater than the accepted 1.0 mg/l have been reported in drinking water where the copper source is reported to be copper water piping and brass fixtures. Copper will be absorbed over time, and thus first draw water is reported to have the highest concentrations, up to 5.0 or more mg/l. Concentration levels drop with increasing flush time, however depending on the installation, flush times may vary. Higher copper levels are also associated with recently installed copper pipe in new construction or renovations. Copper levels will decrease over time as stable protective oxide layers form resulting in lower dissolution rates.

It is highly recommended that users of any water supply system flush the water for one minute or more when used for drinking. Run the system until the water is at a cold, consistent temperature. Do not drink tepid water or water from the hot water system. Copper levels in recirculated hot water systems may not be acceptable for drinking. In addition to flushing, a good point-of-use drinking water filtration system will improve drinking water quality. Finally, due to the low mineral content and aggressive nature of the local water supply, a personal program of mineral supplements should be considered and consulting a health care professional would be a minimum recommendation.

The Environment

There is a significant amount of current research involving heavy metal contamination of the environment. Research of copper levels and the impact on fish and marine life populations have been studied. Toxicity and tolerance in mice, sheep, and birds have also been studied. Another concern is how copper can enter and spread through the food chain.

High concentrations of copper have been found in the following locations;

  1. Soils around copper production facilities due to deposition of airborne copper dust particulates,
  2. Waste disposal and waste waters from mines or other copper production facilities,
  3. Sludge waste from sewage treatment plants in water outfalls or landfill sites,
  4. Sludge waste spread on agricultural lands.

While absolute tolerance levels for marine, animal and plant life are difficult to quantify, it is generally agreed that these levels are lower than the tolerance levels for humans.

It has been noted that the sewage treatment facility at Annacis Island is unable to remove heavy metals and that copper concentrations at the Iona Island outfall are at levels toxic to marine life. In 1998 there was a reported outbreak of copper intoxication which poisoned a flock of sheep in eastern Ontario. The source of the copper contamination was not specified and was reported to be investigated by the Ontario Sheep Marketing Agency. There are reports that mice populations inhabiting copper mines and around copper production facilities exhibit high levels of copper in their liver and tissue. These mice are food for birds of prey (owls, hawks, falcons) and other carnivorous animals and provide a possible route of metal exposure into the food chain. The effects of this type of exposure have not been determined.

[1] "Agency for Toxic Substances and Disease Registry, Public Health Statement", ATSDR Public Health Statement, December 1990, http://www.atsdr.cdc,gov/ToxProfiles/phs9008.html, p1

[2] Ibid, p 4

[3] "Guidelines for Canadian Drinking Water Quality, Sixth Ed.", 1996.

[4]"Gastrointestinal Upsets and New Copper Plumbing - Is there a Connection?", Wisconsin Medical Journal, Lynda Knobeloch et al, January 1998.

[5]"Agency for Toxic Substances and Disease Registry, Public Health Statement", ATSDR Public Health Statement, December 1990, http://www.atsdr.cdc,gov/ToxProfiles/phs9008.html, p3

[6]"Odyssey Clinical Studies Heavy Metal Detoxification" as received October 10/00, http://www.odysseyclinicalstudies.com/ p1

The above excerpt was taken from a privately published report: "Corrosion of Copper Water Pipe in the GVRD pH or not pH? This is The Question, Duane M. Tilden, P.Eng. December, 2000 To obtain a copy of the full report please contact [email protected] for details.

 Coming Soon: The Great Copper Debate!

a Crown Mechanical Consulting, Tuesday, December 10, 2001

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