Sapna Gupta, Associate Professor
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CH 318/Spring 2006
MWF 9:00 -9:50
AM
Room 317

Organic Chemistry II

TextOrganic Chemistry. Solomon and Fryhle, 8th ed. John Wiley, 2003 (ISBN: 0-471-41799-8)
Highly Recommended: Organic Chemistry as a Second Language, Dr. David R. Klein, (ISBN: 0-471-27235-3)

COURSE DESCRIPTION: Application of principles learned in CH 317 to members of each homologous series. Importance of organic compounds in our daily lives. Introduction to biorganic chemistry (amino acids, nuclear bases, carbohydrates, lipids)

EDUCATIONAL PHILOSOPHY: My main objective is to transfer adequate and sufficient amount of knowledge to all the students at the appropriate levels: a) make sure that students understand the idea I am trying to convey, b) prepare students for the next level of education, c) develop the understanding of students, such that they adapt the process of thinking rather than memorizing facts and principles, d) develop practical skills and techniques to work confidently in laboratories, e) demonstrate how chemistry is part of their daily lives, and f) to use alternative and diverse methods of teaching to keep students motivated and interested during the course of their study in the semester, and hopefully for the rest of their lives.


COURSE OBJECTIVES

1. To learn and apply spectroscopic analysis (NMR, UV-Vis, IR, GC-MS etc) of organic compounds.

2. To learn the nomenclature of conjugated systems, phenols and the following homologous series: aromatic, aldehydes and ketones, carboxylic acids and its derivatives, amines.

3. To learn synthesis, properties, reactions and applications of the above mentioned classes of compounds.

4. To connect the information learned (nomenclature, synthesis and reactions) in CH317 to CH318.

5. To apply the knowledge learned in CH317 and CH 318, of synthesis and reactions, to biological compounds eg carbohydrates, proteins and lipids.


COURSE ASSESSMENT

Quizzes: there will be a number of pop quizzes during the semester. Most quizzes will be 5-10 mins long.

Web Quizzes: there will also be some electronic quizzes on the Course Compass web page.

Homework: this will be assigned during the end of the chapter in class

Exams: there will be three mid-terms and one final exam. The midterms are non-comprehensive, however the final will be a comprehensive exam

Attendance: you are advised to attend all classes. Two weeks of consecutive absences will lead to administrative withdrawal from the class. Attendance is part of your class participation grade


GRADING PLAN

45% 3 mid term exams (15% each) on 3 Feb, 3 March and 7 April; each exam will be one hour long, not comprehensive
25% 1 Final Exam: 3 May, 10:15-12:15 pm. 2 hours long and comprehensive
9% Quizzes You may expect a 5 min quiz in every class. In addition there will weekly quizzes, which will be 10‑15 mins long. All these collectively make up the 9%.
6% Electronic quizzes: on the CourseCompass web site
10% Homework: will be assigned in the class throughout the semester
5% Class participation: attendance, participation in the class and general etiquette
A 85 and above
B 75-84
C 60-74
D 50-59
F 49 and below

ACADEMIC HONESTY: Academic Honesty is required of all members of a learning community. Hence, Park will not tolerate cheating or plagiarism on tests, examinations, papers, or other course assignments. Learners who engage in such dishonesty may be given failing grades or expelled from Park.

PLAGIARISM: Plagiarism�the appropriation or imitation of the language or ideas of another person and presenting them as one�s original work�sometimes occurs through carelessness or ignorance. Learners who are uncertain about proper documentation of sources should consult their facilitator.

ATTENDANCE POLICY: Instructors are required to keep attendance records and report absences. The instructor can excuse absences for cogent reasons, however missed work cannot be made up unless permitted by the instructor. In the event of two consecutive weeks of unexcused absences in a term of enrollment, the student will be administratively withdrawn, resulting in a grade of �F�. An Incomplete will not be issued to a student who has unexcused or excessive absences recorded for a course. Students receiving Military Tuition Assistance (TA) or Veterans Administration (VA) educational benefits must not exceed three unexcused absences in the term of enrollment. Excessive absences will be reported to the appropriate agency and may result in a monetary penalty to the student. Reports of F grade (attendance or academic) resulting from excessive absence for students receiving financial assistance from agencies not mentioned above will be reported to the appropriate agency.

Please Note: Attendance is part of your grade. Unexcused absences:

Of 5 lectures will result in 3% deduction of overall grade
Of 9 lectures will result in a F in the class

LATE SUBMISSION OF COURSE MATERIALS

  • Class quizzes and exams cannot be made up.
  • Homework and internet quizzes are to submitted on the dates given before the class starts. 20% of the score will be deducted for each day the assignment is submitted late.
  • Assignments submitted after one week will not be accepted for grading.
  • Assignments submitted after the assignment has been given back to the class will not be graded.

CLASSROOM RULES OF CONDUCT

1) There will be no drinking or eating in the classroom, unless approved by the instructor.
2) All assignments submitted should be stapled, neat and legible.
3) Tardiness in coming to class, late submission of homework and quizzes will constitute in a loss of class participation points.
4) Rude behaviour towards the instructor or a colleague will not be tolerated.
5) Students should avail all opportunities to participate in class, a disinterest in class participation will lead to loss of class participation points.
6) It is the student�s responsibility to keep solving problems at the end of the chapter and within the chapter as the course progresses. (The problems will help you understand the subject better and also give you insight on what is expected of you in exams.)
7) There will be absolutely no makeup exams or quizzes, hence students are advised to keep exam days free of any other commitment. Exam dates have been set in the syllabus, unless an absolute emergency arises (from the instructors point of view) none of those dates will be changed


COURSE TOPICS

Chapter Topics Assignment
Chapter 12 Oxidation-Reduction and Organometallic chemistry:
Grignard reagent and reaction
Practice: 4,5, 6, 9, 10
Submit: 11, 13-18, 20, 25
Chapter 13 Conjugated systems:
Polyenes, Resonance, Diels Alder Reaction
Practice: 1-6, 9, 12
Submit: 16-19, 24, 25, 33
Chapters 9, 2.16
  and 13.9
Structure determination using spectroscopic techniques:
Nuclear magnetic resonance, Infra-red spectroscopy, Ultraviolet spectroscopy, Mass Spectroscopy, Gas chromatography, Elemental Analysis.
Chapter 9:
Practice: 1,2,4,5,7,8
Submit: 29,31,36 
 
Chapter 14 Aromatic Compounds:
Introduction to aromaticity; Rules for aromaticity, Heteroaromatic compounds, Spectroscopy of aromatic compounds
Practice: 1,3,4,14;
Submit: 16,18,23,25,29
Chapter 15

 

Reactions ofAromatic Compounds:
Revision of electrophilic substitution; Substitution on benzene ring; Substituent effect on disubstitution.
Chapter 15:
Practice: 1,3,5,6,7abc,9,14,16,19,20; Submit:26,27,28,29adhj,30abcdg, 31acfi,37,51
Chapters 16,
17, 18 and 20
Nomenclature, synthesis and reactions of Carbonyl compounds aldehydes and ketones, amines and carboxylic acids. Chapter 16 Aldehydes and Ketones: Practice:1,2,3,4abdfk,5,6,8,9,12,15,17abdf;
Submit: 23,24abcdefghin, repeat with 25, 26,27a, 28abcehimn, 31, 32, 38,40,42.

Chapter 17 Aldol Reactions: Practice:7,8,9,10,11,12,19,25,35b,37;
Submit: 28abcdgjkl,repeat with 29,31abdg,33.

Chapter 18 Carboxylic Acids:
Practice: 1,4,5abdehi,6,7,8,9,14, 17ac;
Submit: 3,19abcdefgmp, 20abcfhi,21acd, 22, 23, 24abdegil, 25abcd, 29acdf, 32ade, 36ac, 37.

Chapter 20 Amines:
Practice: 2,5,7,8abc, 11,14,17;
Submit: 21abcdefgjmst, 22abdhln, 23abceg,24, 25abd, 26abcegiklm, 27ad,30abcdij, 31abdflq, 40
 

Chapter 21 Phenols Nomenclature and properties: (physical and chemical) phenols, Synthesis and Specific reactions of phenols Chapter 21: Practice: 1, 3, 6;
Submit:13, 14, 15
Chapters 22, 23, 24 and 25 Biomolecules

Introduction to: Carbohydrates, Lipids, Proteins and Nucleic acids.

Chapter 22:
Practice:1,6,7,9abce,20.

Chapter 23: Practice:2a,3ae,4,8,12adfj,19,21.
 


GOOD LINKS

Nomenclature

Quizzes

  http://www.mhhe.com/physsci/chemistry/carey/student/olc/index.htm. Try this text book notes. There are also quizzes at the end of chapter. See how you perform on them. 
 

From Carey Book Site: http://highered.mcgraw-hill.com/sites/0072424583/student_view0/chapter_tutorials.html

 

Organic Chemistry Practice at MSU: http://www.cem.msu.edu/~reusch/VirtualText/Questions/problems.htm

Tests

Good Notes

Spectroscopy

Practice Problems and Databases

Molecules:


Model Sets

Hints on buying a model set:

1) buy it only if you really think you need it.
2) you can get a larger kit and share with a friend.
3) you may not need a model set if you are not going to be a chemistry major
4) make sure you see (even if its a picture) the model set before you buy it.
5) try not to buy a model that will break away eg the with wooden pieces.
6) if you are planning to take more chemistry/biology courses, buy a kit that can be used for both organic and inorganic chemistry
7) you can always sell your model kit next year if you think you will not need it.

Here are some places to start looking

1) MolyMod: http://www.molymod.com/

2) Darling Models: http://www.darlingmodels.com/ccp51/cgi-bin/cp-app.cgi not the best kind, hard to rotate bonds.

3) Another Place to get MolyMod models: http://www.indigo.com/models/molymod-molecular-model-sets.html (62009 is the best one to buy)

4) Prentice Hall Model Set: this is the most professional one.
http://www.amazon.com/exec/obidos/tg/detail/-/0205081363/102-9171052-0038565?v=glance
http://www.prenhall.com/list_ac/searches/MC0511.html

5) UMKC bookstore sells model sets, you may want to take a look there also, if its convenient for you.

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