Below is the list of the signature characters and their respective players.
| Character | Player | Level | Team |
| Ichigo | |||
| Rukia | |||
| Orihime | |||
| Sado | |||
| Ishida | |||
| Kon | |||
| Urahara | |||
| Yoruichi | |||
| Ururu | |||
| Renji | |||
| Byakuya | Eric | 上级 | 邓黄二佬 |
| Hitsugaya | Johnny | 上级 | 邓黄二佬 |
| Rangiku | |||
| Ikkaku | |||
| Yumichika | |||
| Yachiru | |||
| Kenpachi | Ziheng | 初级 | The Bodyguard |
| Komamura | Ben | 初级 | Kawaii Kemono |
| Shuuhei | |||
| Kira | |||
| Hinamori | |||
| Soifon | Asanga | 初级 | The Saviors |
| Kurotsuchi | |||
| Shunsui | |||
| Ukitake | |||
| Yamamoto | |||
| Aizen | |||
| Gin | |||
| Shinji | Yi Liang | 初级 | TEAM NIL |
| Hiyori | |||
| Tousen | |||
| Ulquiorra | Bryan | 初级 | ADVENT |
| Grimmjow | |||
| Luppi | |||
| Yami | |||
| Hollow Ichigo |
*Level is categorized according to battle ability.
上级 - Able to defeat a hard level opponent one-on-one
中级 - Able to defeat a normal level opponent one-on-one
初
级 - Able to defeat a easy level opponent one--on-one