Dubnium

• Atomic Number: 105

  Atomic Symbol: Db

  Atomic Weight: (262)

History:

• In 1967 G.N. Flerov reported that a Soviet team working at the Joint Institute for Nuclear Research at Dubna may have produced a few atoms of 260-105 and 261-105 by bombarding 243Am with 22Ne. Their evidence was based on time-coincidence measurements of alpha energies. More recently, it was reported that early in 1970 Dubna scientists synthesized Element 105 and that by the end of April 1970 "had investigated all the types of decay of the new element and had determined its chemical properties." The Soviet group had not proposed a name for 105. In late April 1970, it was announced that Ghiorso, Nurmia, Haris, K.A.Y. Eskola, and P.L. Eskola, working at the University of California at Berkeley, had positively identified Element 105. The discovery was made by bombarding a target of 249Cf with a beam of 84 MeV nitrogen nuclei in the Heavy Ion Linear Accelerator (HILAC). When a 15N nuclear is absorbed by a 249Cf nucleus, four neutrongs are emitted and a new atom of 260-105 with a half-life of 1.6 s is formed. While the first atoms of Element 105 are said to have been detected conclusively on March 5, 1970, there is evidence that Element 105 had been formed in Berkeley experiments a year earlier by the method described. Ghiorso and his associates have attempted to confirm Soviet findings by more sophisticated methods without success. The Berkeley Group proposed the name hahnium, after the late German scientist Otto Hahn (1879-1968), and Ha for the chemical symbol. n October 1971, it was announced that two new isotopes of Element 105 were synthesized with the heavy ion linear accelerator by A. Ghiorso and co-workers a Berkeley. Element 261-105 was produced both by bombarding 250Cf with 15N and by bombarding 249Bk with 16O. The isotope emits 8.93-MeV alpha particles and decays to 257Lr with a half-life of about 1.8 s. Element 262-105 was produced by bombarding 249Bk with 18O. It emits 8.45 MeV alpha particles and decays to 258Lr with a half-life of about 40 s. Seven isotopes of Element 105 (unnilpentium) are now recognized.