Chetak's Explosive Pages

I had warned most of you that my home pages consists of many a thing that may irk a lot of you. If so please leave before my ideas corrupt you to the core. To be serious i have included the stuff about the explosives so that even a layman could know about the same in case he comes across some stuff and thus alert the authorities. The way things are going about in today's world , anything is possible.

Bombs and Other Explosives

General

Few military bombs (other than those dropped by aircraft) are currently manufactured on the scale and with the diversity encountered in the Second World War. The exception to this generalization is the mine - both the anti-personnel and anti-tank mine. Mines can be adapted without too much difficulty with average combat-engineer experience. Some 300 different types of mines are buried under the soil, killing tens of thousands every year.

Most bombs assembled by terrorists are improvised. The raw material required for explosives is stolen or misappropriated from military or commercial blasting supplies, or made from fertilizer and other readily available household ingredients. Such assembled bombs are known as Improvised Explosive Devices (IEDs).

Components

IEDs have a main charge, which is attached to a fuse. The fuse is attached to a trigger. In some types of IEDs, these three components are almost integrated into a single whole. The trigger is the part which activates the fuse. The fuse ignites the charge, causing the explosion. The explosion consists of a violent pulse of blast and shock waves. The effects of the IED are sometimes worsened by the addition of material, such as scrap iron or ball-bearings. Sometimes the trigger is not the only component that activates the fuse; there is also an anti-handling device that triggers the fuse when the IED is handled or moved. The purpose of most IEDs is to kill or maim. Some IEDs, known as incendiaries, are intended to cause damage or destruction by fire. The format of the charge in some IEDs (some of which have no casing to contain the components of the IED) can be shaped or directional, rendering a measure of control over the explosion. Anti-personnel mines and other types of mines have been adapted by terrorists to suit their purposes.

Favoured Explosive Charges

Methods / Triggers used to detonate an IED

Examples of IEDs

 

CLASSIFICATION EXPLOSIVE COLOR USES RATE OF DETONATION REMARKS

Low Explosives

Black Powder Black, gray or cocoa brown Safety fuse, Muzzle loaders 1,312 feet per second very sensitive to friction heat and shock
Smokeless Powder Light brown to black Small arms, mortars, rockets Rapid burning very sensitive to friction heat and shock

Primary Explosives

Lead Azide White to buff gray Detonators, priming compositions 13,400 to 17,000 feet per second very sensitive to friction heat and shock
Lead Styphnate White to buff gray Priming compositions 17,100 Feet per second very sensitive to friction heat and shock
Mercury Fulminate Light orange to reddish brown Detonators, priming compositions 11,500 to 21,100 feet per second very sensitive to friction heat and shock
Tetracene Pale yellow Detonators, priming compositions Less than 13,100 feet per second sensitive to shock and heat.  Used in combination with other explosives

Secondary Explosives

Amatol Buff to yellow to dark brown Main charge for bombs, projectiles 14,800 to 21,100 feet per second Developed during WWII to conserve TNT
Ammonal Gray Projectile filler 17,700 feet per second water soluable
Ammonium Nitrate White but may be dyed other colors Ingredient of many explosive mixtures 3,300 to 8,200 feet per second Must be kept cool
Ammonium Picrate yellow to orange to red Armor piercing projectiles and bombs 22,500 feet per second Relatively insensitive to shock and friction
Astrolite White pellets Demolition 2,600 to 26, 200 feet per second Inert until mixed.   Do not use with Tetryl
C-4 White to light brown Plastic demolition explosive 26,400 feet per second Insensitive to impact and friction
Cyclotol Buff to yellow to brown Fragmentation bombs, projectiles 25,900 to 26,400 feet per second Excellent for blast effects
Flex-x any color--Usually olive drab or red Cutting charges 22,300 feet per second Flexible, waterproof, insensitve to shock

Secondary Explosives

HBX (Torpex) Gray Main charge filler for underwater bombs and torpedoes 22,700 to 23,700 feet per second Excellent for blast effects
HMX White Mixed with TNT in high blast warheads 29,900 feet per second By product of RDX manufacture
Kinepak Powder is white, the liquid is usually pink Construction 20,100 feet per second Inert until mixed
Minol gray Filler for bombs and depth charges 19,100 to 19,700 feet per second Comparable to TNT in sensitivity to initiation
Nitro-Cellulose White Blasting, smokeless powder 21,900 feet per second Used in flashless powder
Nitro-glycerin Clear to amber.   Red fumes mean "Beware" Demolition, ingredient in dynamite 4,900 to 25,400 feet per second Can be absorbed through skin causing headache

Secondary Explosives

Nitro-guanidine White to yellow Propellant and bursting charge ingredient 25,100 feet per second One of the least sensitive military explosives
Nitro-starch white Mortar shells, grenades 16,00 feet per second Another form of Nitro-cellulose
Octol Buff Projectile and bomb filler 27,500 to 28,300 feet per second Excellent for blast effects
Pentolite White to yellow to gray Shape charges, boosters 24,500 feet per second Presence of   grit increases impact sensitivity
PETN white unless dyed Det cord, blasting caps, primer 27,200 feet per second Presence of  grit increases impact sensitivity
Picratol Yellow to brownish yellow Armor piercing projectiles and bombs 22,900 feet per second Insensitive to initiation

Secondary Explosives

Picric acid Cream to yellow to red Alternative filler 19,00 feet per second Dangerous when it deteriorates
RDX White but may be dyed Det cord, blasting caps, used to make C-4 26,800 feet per second Not used much until WWII
Tetryl Clear to yellow to gray Booster, blasting caps 25,800 feet per second Colors skin reddish brown and causes rash
Tetrytol Light yellow to buff Bursters, demolition blocks 24,000 to 24,200 feet per second Similar to TNT and Tetryl
TNT Light yellow to brown to light gray Bombs, projectiles, demolition 21,800 to 22,400 feet per second Standard with which all other explosives are measured
Torpex Gray Depth charges, mines 24,600 feet per second Excellent for blast effects
Tritonal Silvergray Bombs 21,200 to 22,000 feet per second More powerful and more sensitive to shock than TNT

 

Dynamite There are hundreds of formulas for dynamite and there is no set standard for detonation speed,   color, or  size.   Dynamite with nitroglycerin as an ingredient is becoming rare.   Nitroglycerin dynamite will crystalize after a long period of storage.   A sudden temperature difference of 3 degrees can cause these crystals to detonate without warning

 The Grand Dad of them all and a boon to the wretched terrorists ( RDX)

Properties

Appearance White solid

Molecular weight 222.1

Melting Temperature 204° C, high but lowers when mixed with TNT

Thermal ignition temp 260° C

Stability High chemical stability, especially compared to TNT

Solubility Difficult to dissolve in organic liquids

Sensitivity Easily initiated by impact of friction, often coated with oil or wax

History

1899 RDX first prepared by a German named Henning for use in medicine.

1920 RDX first recognised as a possible explosive.

1940 A continuous method for the preparation of RDX was developed.

 

RDX was used with TNT to fill bombs and shells during the Second World War by both sides in order to create more powerful weapons.

 

Structure

Synthesis

The best way to make RDX is to use the compound pictured above and react it with ammonium nitrate and concentrated nitric acid. The mixture is warmed and when cold water is added, RDX is precipitated. The mechanism for this reaction is very complicated.

Decomposition Products

RDX, like TNT, does not have enough oxygen in its molecular formula to completely oxidize everything during an explosion. It is only after contact with the atmospheric oxygen that can allow complete combustion to occur. Below is the decomposition reaction of RDX.

 

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