Paul Caginalp

 

Chemistry

Grades 10, 11, 12

Regents

2/25-3/5

Solutions unit

Abstract:  The unit includes solid, liquid, and gaseous solutions.  The focus however, is on liquid solutions.  Colligative properties, solubility curves, measures of concentration, and factors affecting solubility will all be examined.  The unit will start with vocabulary, and a general conceptualization of what the vocabulary does for the unit.  As we move along the students will become more adept at using the vocabulary, and will be able to tackle the ideas of factors in solubility, dissociation equations, solubility curves, concentration, and colligative properties in that order. 

 

Topic list

Solutions

            Factors affecting solubility

                        Gases versus Solids

            Dissociation equations

                        Solubility products

            Solubility curves

            Concentration

            Colligative properties

 

Vocabulary words

Solubility-The affinity or lack thereof for a solid or gas to dissolve.

Solute-The solid or gas (generally) that is added to the solution, or in the minority.

Solvent-The majority of a solution

Concentration-a measure of how dilute or concentrated a solution is

Saturated-the point where no more solute can be added to a solution

Dissociated-the tendency of ionic compounds to split into ions in a solution

Molarity-the most popular measure of concentration, given in moles per liter

Boiling Point elevation-the amount that a solutions boiling point raises after addition of a solute

Freezing Point Depression-the amount that a solutions freezing point drops after addition of a solute

Precipitate-the solute in a solution that is not dissolved

Electrolyte-any ion in solution that can carry electric current

 

Key Activities

Creative descriptions of vocabulary

Guided practice  I will give the students time to practice needed skills in class by having them work on worksheets while I can still guide them through a step if I need to.  I will use this as my way of transferring responsibility to the students. 

Two Quizzes

Unit Test

Labs-One on saturated solutions, one on solubility curves, and one on concentration

Pieces of the real world

Examples of solutions; amalgams, alloys…

Freezing point depression with snow and ice on roads

Soda bottles, and the solubility of carbonation

Electrolytes in the body

 

Big Ideas

The most important ideas for this unit for these kids are what is going to be tested on the regents.  The most common questions for solutions on the regents are on the factors affecting solubility, the solubility curves, and molarity.  I also plan to include the reasons for dissociation as one of my big ideas, but other than that I will stick fairly close to the big ideas that the regents identifies.  The students will be able to tell what will happen if a solution is heated, pressurized, or stirred.  They will also be able to read solubility curves.  The solubility curves are easy to read, but they have to watch out for how much water the question dictates.  Solubility curves are made at 100g of water.  If more water is present, more solute can be added.  For molarity they to be able to convert easily from moles to liters, and back.  Understanding the reason for dissociation is a little harder, but I think they can manage it.  They need to realize that water molecules are polar, and that the polar molecules are what pulls the ionic crystals apart. 

Standards and objectives:

Mixtures are composed of two or more different substances that can be separated by physical means.  When different substances are mixed together, a homogenous or heterogenous mixture is formed.

Proportions in a mixture can be varied.  Each component in a mixture retains original properties.

A solution is a homogenous mixture of a solute dissolved in a solvent.  The solubility of a solute in a given amount of solvent is dependent on the temperature, the pressure, and the chemical nature of the solute and solvent.

Concentration of a solution may be expressed as molarity percent mass, or parts per million.

The addition of a nonvolatile solute to a solvent causes the boiling point of the solvent to increase and the freezing point of the solvent to decrease.  The greater the concentration of solute particles the greater the effect. 

Students will be able to answer regents questions about solutions

Students will be able to identify solutions, and describe their properties.

Students will be able to explain why a pickle lights up and a cucumber doesn’t in terms of electrolytes and the properties of solutions.

 

Central question and Concept Map

In what different ways do compounds mix?  What difference does it make?

 

 

Oval: Amalgam
Oval: Alloy

Oval: Suspension

                                                    Mercury alloy

 


             

 Type of solid solution

Oval: Solid                                                                                               

           

Oval: Mixture

                                                                                   

Non heterogeneous mixture

Phase of solution

 

Oval: Solution                             Homogenous mixture

Oval: GaseousOval: Liquid                       

                                    Phase of

                                   

                                    Solution

 

Factor of solubility

 
Oval: PressureOval: Solubility
Curve
trends
Oval: TemperaturePhase of solution                                     Factor of solubility         known traits

 

 

 

                                                                                   

 

 

 


                Factor of

Oval: Colligative propertiesOval: ConcentrationOval: KspOval: Dissociation of solids                   solubility                known traits                                                    important effect

                                                                                                                        on ionic solids

 

 

 

 

 

                                                Determines the extent

                                                of dissociation

           

                                                                                    measure of solids

                                                                                    in solution                     One type of

                                                                                                                        dissociation

 

 

                        Effect of ions in

Oval: Electrolytes                        solution                                                

 

 

Assessment

For preassessment I want the students to make the vocab their own.  I plan to do this by letting them creatively display their ideas of the vocab.  I want them to come up with a picture, song, activity, sculpture, or other way of demonstrating a vocab word.  They will work in groups of 3-4 and each group will be assigned 2-3 words.  They will then have 15 minutes to be creative, using whatever they can find in the room.  This should air any misconceptions, as well as providing an interesting way for them to learn the vocab.  It is my hope that this will get them to the comprehension stage of Blooms taxonomy.  I think that this understanding will carry through this unit because this unit is based heavily on vocab.  This should enable students to identify solutions and their properties, and answer regents questions.  To make sure my students achieve these objectives, I will give them a test at the end of the unit that consists of half regents questions, and half of my own questions.  The purpose of this is to get them accustomed to the types of questions that the regents asks while still asking good questions. 

            Another preassessment task is to electrify a pickle and a cucumber, and not provide the answer of why the pickle lights up till a day later.  This provides them time to reason it out, and time to get really anxious to know the answer.  I will either do this the first day of the unit, or the second, depending on how well the creative group does with the term electrolytes.  I will use this to lead into a small discussion of how electrolytes affect our bodies and why Gatorade has them.  The cumulative assessment for this objective will be in the test, as one of my questions.

            Finally, to help students pick out solutions and their properties, I am starting them off with a homework assignment to pick out and categorize 8 solutions that they can find at home.  They will then group with a partner in class, and discuss the solutions they picked and categorized with regard to accuracy.  The final assessment for this objective will come in the form of a lab, as the students attempt to make their own solubility curve.

This will force them to make their own curve for a substance, see what factors affect solubility, and how their substance acts.

Learning cycle patterns

The first assessment listed above fits the learning cycle well.  I plan to model the first vocab word creatively.  The word that I have chosen to do this with is molarity.  I plan to make a sculpture o’ molarity.  I have a 1L soda bottle, and a stuffed mole that I will place atop it.  Moles per liter.  The next vocab word, solubility, I plan to enlist the students help in showing.  I will ask for suggestions, and then when we have finished I will ask them to help me rate it for effectiveness.  By asking them to rate it for effectiveness and accuracy I hope to ensure that their group examples will be rated as well.  Based on how well they are taking to the subject, I will either turn them loose to their own creative devices, or do another example with their input, but less of my input. The other place I expect to do a complete learning cycle is with solubility curves.  The students will be doing questions on solubility curves by day three of the unit.  These questions are fairly easy to answer, with one or two tricks thrown in to make the kids read carefully.  I will model a question, and show them the pitfalls of not reading carefully in a second example, but then I expect them to do it on their own.  The responsibility for solubility curves will be wholly theirs when they have completed their lab on solubility curves, which could take place anywhere from the first, to third day of the unit.  (they do the lab then, but they don’t hand it in till the next week, which should be past the solubility curve day.)

     


Class day

Topic list

Vocab

Demo

Lab

Activities

HW

1

Vocabulary

Solution introduction

Solubility of gases and solids in liquids

All listed above, and Homogeneous.

 

Pickle?

 

Solubility curves

Creative vocabulary

Scavenger hunt of household solutions

2

Dissociation equations

Solubility products

Low concentration saturated solutions

Dilute

Concentrated

Solubility constant

Dissociation

Pickle?

 

Guided practice with dissociation

Ion-molecule polarity fun

Learning the tables and dissociation practice

3

Solubility curves

Trends of solubility

Review for quiz

 

Blue flask white flask?

 

Group Practice with solubility curves

Ticket out of here.

More solubility curve fun, and the lab.

4

Molarity

Colligative properties

Vapor pressure

Vapor pressure

 

Ammonia

Revisit to creative vocab.  Group Molarity practice

Ticket out of here.

Molarity practice

Lab

5

Quiz on first 3 days

 

 

 

 

 

6

PPM

% composition by mass

PPM

 

 

 

Group Practice for ppm and % composition.  Ticket out of here

Practice for ppm and % composition

7

Quiz

 

 

Determination of Iron

 

 

8

Test

 

 

 

 

 


Selected Plans

Creative vocab activity:

I want the students to take away an interesting way of remembering the vocabulary.  Moreover, I want them to remember the vocabulary.  This first part of the unit should be a nice precursor, and set up success for the rest of the unit.  The activity should take students slightly out of their comfort zone, so I am letting them choose their own groups in hopes that their friends will make them more bold and willing to take risks.  I want them to really reach out and be creative with the project, so I am trying to limit them as little as possible.  I also want them to look critically at each other’s work and make suggestions.  I think that the class as a whole should create the meaning of the vocab so that it comes alive for them.  After I model it for them once or twice I expect them to take off running in their groups, I think it will be an engaging activity. 

 

Foreshadowing, introduction

I will be modeling the activity, and trying to get the students to get more and more involved after the first word.

Figuring out what they have to do, then giving ideas as we move to the second or third word. 

Activities of the Lesson

Walking around, looking for misconceptions and trying to direct them towards good conceptions of the vocab

Working together to create a class set of owned vocabulary

Reflection, summary, Conclusion

Guiding the students to analyze each others creative conceptions

The hard part, aka analyzing each others work for accuracy.

 

 

Day 4-molarity lesson

In contrast to the lesson above, this lesson will be much more traditional.  Molarity is one of the concepts that they absolutely must know for the regents, and I want them to really have it down.  Chemists classify nearly every solution in molarity, with the exception of environmental concerns, because they are usually such small amounts.  This lesson will consist of mostly guided practice, with some group work and practice.

Materials

A worksheet on molarity, to be finished for homework

Activities

Foreshadowing, Introduction

Reminder of the sculpture of molarity, moving through the guided notes on molarity

Filling out the guided notes on molarity.

Activities of the lesson

I will do one example of a molarity problem, paying close attention to keeping my units straight, and canceling units.  I will then move through the student groups, looking for signs of misunderstanding on the worksheet or students that are completely perplexed.

The Iron lab also incorporates a lot of concentration problems, so that lab will fit in well here. 

Doing more and more of the problems on their own, until they finally break into groups and work on the worksheet.

Reflection, Summary, Conclusion

Remind them that the sheet is homework, take note as opportunity permits of students struggling with the worksheet, so I know who to look towards the next day when going over HW.  

I also want to do “ticket out of here” on this day so I get an idea of what they still need help on.

Finishing up a last question, or working on the lab and getting ready to go to their next class.

 

 

 

Lesson day 3

Solubility curves and trends: The movement through the solubility curves will have to be slow and careful, because they make up a good part of my tests and quizzes, as well as being tested on frequently in the regents.  After moving through the notes on solubility curves, I plan to do a demo to introduce trends.  There is a solution that turns blue when air is introduced to the solution.  I plan to show them that pressure and cooling make the color appear/stay longer, while heating makes the solution turn colorless much faster.  I am going to have them write a little observation section, and then a conclusion section.  It will be informal, but I want to see what they come up with.  I am going to collect the papers, and it will count as a HW grade.  Then I will go over trends. 

Materials

Solution, flame, something to increase the pressure, vacuum pump, and an ice bath.

Activities

Foreshadowing, Introduction

To start I am going to ask them to take out a piece of paper, and a pen, and to write down some observations.  If the changes in timing are not noticeable to the naked eye, I am going to have one student with a stopwatch.  I will tell them that the assignment counts as a HW grade, and ask for conclusions after the observations

They will watch the demo, and copy down observations of what is happening.

Activities of the lesson

I will perform many variants of the demo with different variables, and then ask them to write their conclusion on the trends of gases dissolved in liquids.

They will write a conclusion, and hand it in.  Hopefully this will let them experience the pressure aspect of gas dissolution more clearly, as this is usually the more abstract concept.

Reflection, summary, conclusion

I will ask one of the students to share their conclusion, and try to guide it to some trends of gases

I hope one or two of the students will share their views.  I think that having students give their ideas of the trends will cement it more in all their minds.

 

 

Hosted by www.Geocities.ws

1