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    Preparation of 3,4-methylenedioxyphenyl-2-nitropropene (from piperonal)
           by Rhodium - as submitted to Total Synthesis II by Strike
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In Pihkal, Alexander Shulgin mentions that the preparation of MDP-nitropropene 
can be carried out in cold methanol with aqueous sodium hydroxide as the base. 
In fact, this method is even more reliable, and gives higher yields than the 
other method advocated by the dear doctor in his book.

15g of piperonal was dissolved in 40ml of methanol under stirring in a 250ml 
Erlenmeyer flask. When all of the piperonal had dissolved, 7.1g nitroethane was 
added to the solution. The flask was put in a ice/salt-bath with magnetic 
stirring, and when the temperature of the solution had dropped to 0°C, an ice- 
cold solution of 4g of NaOH in 20ml dH2O was added at such a rate that the
temperature never rose above 10°C. A white precipitate formed at the bottom of 
the flask during this addition, which was broken up with a glass rod. The 
stirring was continued for another hour, while the temperature of the solution 
was never allowed to rise above 5°C, and at the end of this time, 100 ml of 
ice-cold dH2O was added to the solution, which caused even more precipitation of 
white solid. The whole slurry was poured into 100 ml of ice-cold 2M HCl solution 
in a 500ml Erlenmeyer flask, which was gently swirled, and there was a slight 
bubbling and fizzing, with the color of the solution shifting from white to blue 
to green to yellow in under a minute. Quite spectacular! When the fizzing had 
subsided, the solution was once again placed in in an ice-bath with magnetic 
stirring. When the temperature had dropped to about 5°C, the solution was clear 
with yellow granules of crude product at the bottom. The granules were filtered 
with suction, and recrystallized from IPA. After air-drying, the canary-yellow 
crystals amounted to a yield of 65-70% of theory.

This nitropropene should be used within a week, or stored in the cold, as
the color fades to a slight orange over a couple of weeks in room
temperature, which is a sure sign of decomposition.

Ref: 	A.T. Shulgin, Pihkal, #100, 
     	A.I. Vogel, Practical Organic Chemistry, 5th Ed.