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Transesterified Biodiesel (fatty acid methyl ester)
In organic chemistry, transesterification is the process of exchanging the alkoxy group of an ester compound by another alcohol. These reactions are often catalyzed by the addition of an acid or base. (wikipedia)
Case study:
What is biodiesel?
Give a background on the history, uses, advantages, and problems with bio-diesel.
Biodiesel is a synthetic liquid fuel that is derived from vegetable or animal oils. The prefix 'bio-' is used to differentiate this fuel from 'petro'diesel, a fossil fuel used for a variety of purposes, notably as a chemical energy source for internal combustion engines.
What are the properties of a fuel that make it desirable for use in an automobile diesel engine?
Start with the chemical reaction (C16H34 + O2 → CO2 + H2O) and describe how this is turned into mechanical energy. The average chemical formula for common diesel fuel is C12H26, ranging from approx. C10H22 to C15H32
What are the physical properties of a fuel that aid the functioning of the engine?
- Flash point: the lowest temperature at which a liquid can form an ignitable mixture in air near the surface of the liquid. The lower the flash point, the easier it is to ignite the material.
- Viscosity: the resistance a material has to change in form. This property can be thought of as an internal friction or the ability of it to flow.
- Boiling point: the temperature at which a liquid changes to a gas (vapor) at normal atmospheric pressure
- Melting point: the temperature at which the vapour pressure of the solid and the liquid are the same and the presssure totals one atmosphere.
- Gel point: related to viscosity
- Energy in joules (wick lamp)
- Lubricity
- Reactivity with mechanical components (piston rings, cylinder bores, supply lines, fuel tank, filters)
- Safe handling by humans
- Emissions (CO2, H2O, CO, hydrocarbons, NOx, particulate matter, sulfur oxides)
Analyze properties of fuel for automobile gasoline engine
...Long haul truck diesel engine
...Gas turbine jet engine
...Residential forced air gas furnace
...Water boilers for home heating
If bio-diesel is manufactured from different ingredients how do the resulting fuels compare in terms of:
- Cost
- Performance
- By-products
- Ease of manufacture
- Availability of ingredients in a location
Part I: Production of test fuels (___ hours)
Biodiesel (___ varieties)
- Alcohol: methanol (CH3OH) or ethanol (C2H5OH)
- Alkaline lye: NaOH or KOH
- Oil: vegetable or animal derived (multiple oils)
Produce or procure standard fuels for each engine under review.
As far as your lab testing, it would be great to find out what the composition of the glycerine waste product is when you use waste vegetable oil, pure gylcerine is clear and the stuff we produce as waste is thick black and gelatinous. (This question is from Luis M. at Denver Biofuels Co-op)
Part II: Testing properties of the fuels (___ hours)
Test the properties pertinent to each of the engines under study.
Analysis:
Compare the properties of the bio-diesel with petrodiesel.
Investigate anti-gel additives for cold temperatures (biodiesel products have a problem of gelling when the temperatures fall below 40°F).
Web resources
Wikipedia background articles:
Manufacturing guides:
http://www.chem.vt.edu/RVGS/ACT/lab/Experiments/Exp_11-Biodiesel.html
http://chemeducator.org/bibs/0010002/1020130sm.htm
Information about diesel fuel properties
Possible labs:
http://jchemed.chem.wisc.edu/Journal/Issues/2006/Feb/abs257.html
http://www.chemistry.org/portal/a/c/s/1/resources?id=c373e9f7186084f98f6a4fd8fe800100
Alex Kelley
Spring 2006
Harold Washington College
Chemistry 201 (CDE) -- Prof. Thomas Higgins
[email protected]
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